184276
2-溴苄醇
99%
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关于此项目
线性分子式:
BrC6H4CH2OH
化学文摘社编号:
分子量:
187.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
242-719-4
Beilstein/REAXYS Number:
2243418
MDL number:
Assay:
99%
Form:
solid
InChI key
IOWGHQGLUMEZKG-UHFFFAOYSA-N
InChI
1S/C7H7BrO/c8-7-4-2-1-3-6(7)5-9/h1-4,9H,5H2
SMILES string
OCc1ccccc1Br
assay
99%
form
solid
Quality Level
functional group
bromo, hydroxyl
Application
2-Bromobenzyl alcohol was used in microwave assisted palladium-catalyzed synthesis of phthalides. It was also used in the synthesis of 1-hydroxy-3(1H)-l,2-benzoboroxole.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
Synthesis and structure of benzoboroxoles: novel organoboron heterocycles.
Zhdankin VV, et al.
Tetrahedron Letters, 40(37), 6705-6708 (1999)
Fast microwave promoted palladium-catalyzed synthesis of phthalides from bromobenzyl alcohols utilizing DMF and Mo (CO)6 as carbon monoxide sources.
Wu X, et al.
Tetrahedron Letters, 45(24), 4635-4638 (2004)
Manas K Ghorai et al.
The Journal of organic chemistry, 79(14), 6468-6479 (2014-06-24)
A simple and unpredicted synthetic pathway toward racemic and scalemic tetrahydrodibenzoimidazoazepines has been invented serendipitously proceeding through an S(N)2-type ring-opening of N-activated aziridines with 2-bromobenzylamine followed by a hitherto unprecedented cascade cyclization reaction sequence comprising a Cu-catalyzed cross dehydrogenation C-N
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