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Merck
CN

184462

氯甲酸丁酯

98%

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关于此项目

线性分子式:
ClCOOCH2CH2CH2CH3
化学文摘社编号:
分子量:
136.58
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-750-5
Beilstein/REAXYS Number:
605635
MDL number:
Assay:
98%
Form:
liquid
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InChI key

NRDQFWXVTPZZAZ-UHFFFAOYSA-N

InChI

1S/C5H9ClO2/c1-2-3-4-8-5(6)7/h2-4H2,1H3

SMILES string

CCCCOC(Cl)=O

vapor pressure

2.42 psi ( 20 °C)

assay

98%

form

liquid

refractive index

n20/D 1.412 (lit.)

bp

142 °C (lit.)

density

1.074 g/mL at 25 °C (lit.)

functional group

chloro

storage temp.

2-8°C

Quality Level

Application

  • Butyl chloroformate was used in the synthesis of dextran alkyl carbonates.
  • It was also used in the synthesis of S-tert-alkyl-N,N-alkoxycarbonylmethyl-dithiocarbamate, radical polymerization with reversible addition-fragmentation chain transfer agent.
  • It was used as derivatization reagent in determination of linsidomine in plasma using high-performance liquid chromatographic separation with tandem mass spectrometric detection.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Flam. Liq. 3 - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

100.4 °F - closed cup

flash_point_c

38 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

新产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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F C Sutherland et al.
Journal of pharmaceutical and biomedical analysis, 22(3), 461-467 (2000-04-15)
A sensitive method for the determination of linsidomine in plasma was developed, using high-performance liquid chromatographic (HPLC) separation with tandem mass spectrometric detection. Linsidomine was derivatised with propyl chloroformate and extracted with tert-butyl methyl ether/1,2-dichloroethane (55:45, v/v), back-extracted into HCl
Multiblock copolymer synthesis via controlled radical polymerization in aqueous dispersions. Part 1: Synthesis of S-tert-alkyl-N,N-alkoxycarbonylmethyl-dithiocarbamate.
Bussels R and Koning CE.
Tetrahedron, 61(5), 1167-1174 (2005)
Andrea Y Garzón-Serrano et al.
Journal of forensic sciences, 65(4), 1085-1093 (2020-03-17)
Ammonium nitrate fuel oil is an explosive mixture found in most antipersonnel landmines (APL) buried throughout the Colombian territory. During more than 50 years of internal conflict, the Colombian government has found that trained dogs are the most effective method to
Tomáš Hložek et al.
Journal of analytical toxicology, 40(9), 749-753 (2016-09-04)
A simple, sensitive and robust method for simultaneous determination of antiepileptic drugs (gabapentin, pregabalin and vigabatrin) in human serum using GC-MS was developed and validated for clinical toxicology purposes. This method employs an emerging class of derivatization agents - alkyl
Thomas Elschner et al.
Carbohydrate polymers, 93(1), 216-223 (2013-03-08)
Dextran alkyl carbonates were synthesized applying ethyl chloroformate, butyl chloroformate, butyl fluoroformate and 1H-imidazole-1-carboxylates. The influence of the reaction conditions on the reaction efficiency and the substitution pattern was studied in detail. The structure of the products obtained was clearly

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