184667
(氯甲基)环丙烷
97%
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关于此项目
线性分子式:
C3H5CH2Cl
化学文摘社编号:
分子量:
90.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
227-632-1
MDL number:
Assay:
97%
Form:
liquid
InChI key
ZVTQWXCKQTUVPY-UHFFFAOYSA-N
InChI
1S/C4H7Cl/c5-3-4-1-2-4/h4H,1-3H2
SMILES string
ClCC1CC1
assay
97%
form
liquid
refractive index
n20/D 1.435 (lit.)
bp
87-89 °C (lit.)
density
0.98 g/mL at 25 °C (lit.)
functional group
chloro
General description
(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
Application
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
28.4 °F - closed cup
flash_point_c
-2 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Unexpected reactions of an isolable dialkylsilylene with Haloalkanes.
Ishida S, et al.
Chemistry Letters (Jpn), 11, 1102-1103 (2001)
Easy selective generation of (lithiomethyl) cyclopropane or homoallyllithium by a chlorine-lithium exchange.
Pastor IM, et al.
Tetrahedron Letters, 49(48), 6870-6872 (2008)
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