185396
四氢糠醇
99%
别名:
NSC 15434, 四氢呋喃甲醇
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关于此项目
经验公式（希尔记法）:
C5H10O2
化学文摘社编号:
分子量:
102.13
eCl@ss:
39150702
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-625-6
MDL number:
Beilstein/REAXYS Number:
102723
Assay:
99%
Form:
liquid
InChI key
BSYVTEYKTMYBMK-UHFFFAOYSA-N
InChI
1S/C5H10O2/c6-4-5-2-1-3-7-5/h5-6H,1-4H2
SMILES string
OCC1CCCO1
vapor density
3.52 (vs air)
vapor pressure
2.3 mmHg ( 39 °C)
assay
99%
form
liquid
expl. lim.
9.7 %
refractive index
n20/D 1.452 (lit.)
bp
178 °C (lit.)
mp
−80 °C (lit.)
solubility
acetone: miscible(lit.), alcohol: miscible(lit.), benzene: miscible(lit.), chloroform: miscible(lit.), diethyl ether: miscible(lit.), water: miscible(lit.)
density
1.054 g/mL at 25 °C (lit.)
functional group
ether, hydroxyl
Quality Level
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General description
用 ReOx物种修饰的 Rh/SiO2催化四氢糠醇进行化学选择性氢解，生成 1,5-戊二醇 。其与马来酸盐发生镧介导的 Michael 型加成反应生成烷氧基丁二酸。
Application
采用四氢呋喃醇作为折射率匹配溶剂，以确保流变测量时二氧化硅颗粒呈硬球悬浮 。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Repr. 1B
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 2
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Microstructure and rheological behaviour of electrosterically stabilized silica particle suspensions.
So J-H, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 190(1), 89-98 (2001)
LaIII-lnduced Addition of Tetrahydrofurfuryl Alcohol, Tetrahydropyran-2-ylmethanol, D-Gluconate, Methanol and Ethanol to Maleate.
Quartey EGK, et al.
Acta Chemica Scandinavica, 50, 825-831 (1996)
[Acute poisoning with tetrahydrofurfuryl alcohol combined with methanol].
B F Murashov et al.
Voenno-meditsinskii zhurnal, (10)(10), 32-34 (1983-10-01)
Mutsuko Hirata-Koizumi et al.
Reproductive toxicology (Elmsford, N.Y.), 25(2), 231-238 (2008-01-15)
Twelve male and female rats per group were given tetrahydrofurfuryl alcohol (THFA) by gavage at 0, 15, 50, 150 or 500 mg/kg/day. Males were dosed for 47 days, beginning 14 days before mating, and females were dosed for 42-52 days
T Schräder et al.
Journal of bacteriology, 183(24), 7408-7411 (2001-11-22)
Different aldehyde dehydrogenases (AlDHs) were formed during growth of Ralstonia eutropha Bo on tetrahydrofurfuryl alcohol (THFA). One of these enzymes, AlDH 4, was purified and characterized as a homodimer containing no prosthetic groups, showing a strong substrate inhibition, and having
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