185892
氯甲酸乙酯
97%
别名:
氯甲酸乙酯
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关于此项目
线性分子式:
ClCOOC2H5
化学文摘社编号:
分子量:
108.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-778-5
Beilstein/REAXYS Number:
385653
MDL number:
Assay:
97%
Form:
liquid
vapor density
3.74 (vs air)
Quality Level
vapor pressure
3.42 psi ( 20 °C)
assay
97%
form
liquid
autoignition temp.
842 °F
refractive index
n20/D 1.395 (lit.)
bp
93 °C (lit.)
mp
−81 °C (lit.)
solubility
alcohol: miscible, benzene: miscible, chloroform: miscible, diethyl ether: miscible, water: insoluble
density
1.135 g/mL at 25 °C (lit.)
functional group
chloro
SMILES string
CCOC(Cl)=O
InChI
1S/C3H5ClO2/c1-2-6-3(4)5/h2H2,1H3
InChI key
RIFGWPKJUGCATF-UHFFFAOYSA-N
Application
- 氯甲酸乙酯用于合成腈氧化物。
- 其已被用作衍生化试剂，以研究衍生化反应过程中手性非甾体类抗炎药的立体化学转化。
- 它在通过浸笔纳米光刻技术生成纳米级模板的过程中，被用于进行灵活的模板开发。
- 通过二维气相色谱法将其用作氨基酸对映体分析中的衍生化试剂。
- 它还可与氨和氰尿酰氯一起使用以将羧酸转化为腈。
Packaging
用于通过二维气相色谱对氨基酸进行对映体分析的衍生化试剂。还与氨和氰尿酰氯共同用于将羧酸转化为腈类。
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
60.8 °F
flash_point_c
16 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Sezin Erarpat et al.
Journal of separation science, 43(6), 1100-1106 (2019-12-21)
A green and fast analytical method for the determination of l-methionine in human plasma is presented in this study. Preconcentration of the analyte was carried out by switchable solvent liquid phase microextraction after ethyl chloroformate derivatization reaction. Instrumental detection of
M R Wright et al.
Journal of chromatography, 616(1), 59-65 (1993-06-23)
A potential problem with chiral derivatization is the possibility of stereochemical conversion during the derivatization reaction. This possibility has been examined using the non-steroidal anti-inflammatory drugs ibuprofen, ketoprofen, etodolac and flurbiprofen. To avoid possible interference from stereochemical impurities, male Sprague-Dawley
Tetrahedron Letters, 48, 1465-1465 (2007)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 185892-2KG | 04061833544945 |
| 185892-100G | 04061838757715 |
| 185892-500G | 04061838757722 |
| 185892-5G | 04061838757739 |
| 185892-PZ | 04061823589611 |