186791
氯乙酸叔丁酯
97%
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关于此项目
线性分子式:
ClCH2COOC(CH3)3
化学文摘社编号:
分子量:
150.60
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-506-1
Beilstein/REAXYS Number:
1753006
MDL number:
Assay:
97%
产品名称
氯乙酸叔丁酯, 97%
InChI key
KUYMVWXKHQSIAS-UHFFFAOYSA-N
InChI
1S/C6H11ClO2/c1-6(2,3)9-5(8)4-7/h4H2,1-3H3
SMILES string
CC(C)(C)OC(=O)CCl
assay
97%
refractive index
n20/D 1.423 (lit.)
bp
48-49 °C/11 mmHg (lit.)
density
1.053 g/mL at 25 °C (lit.)
functional group
chloro
ester
Quality Level
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Application
氯乙酸叔丁酯用于合成：
- 咪唑-1-基-乙酸盐酸盐
- 顺 -二取代氮杂环丙烷酯的合成
- 基于香豆素荧光团的传感器
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
wgk
WGK 1
flash_point_f
114.8 °F
flash_point_c
46 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Substituent dependent fluorescence response of diazacrown-based PET sensors.
Nagy K, et al.
Tetrahedron, 64(27), 6191-6195 (2008)
Santosh Kumar Singh et al.
Beilstein journal of organic chemistry, 4, 42-42 (2008-12-24)
A convenient and practical synthesis of imidazol-1-yl-acetic acid hydrochloride was achieved via N-alkylation of imidazole using tert-butyl chloroacetate followed by a non-aqueous ester cleavage of the resulting imidazol-1-yl-acetic acid tert-butyl ester in the presence of titanium tetrachloride. The synthesized imidazol-1-yl-acetic
E Vedejs et al.
The Journal of organic chemistry, 65(18), 5498-5505 (2000-09-02)
Intermolecular alkylation of the aziridinyl oxazole 20 using PhSO(2)CH(2)CH(2)OTf is possible despite the presence of potentially nucleophilic aziridine nitrogen. The resulting oxazolium salt 22 reacts with BnNMe(3)(+)CN(-) to produce the azomethine ylide 24b via electrocyclic ring opening of an oxazoline
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