187054
4-溴苄醇
99%
别名:
(4-溴苯基)甲醇, (对溴苯基)甲醇, 1-(对溴苯基)甲醇, 1-溴-4-(羟甲基)苯, 4-羟甲基-1-溴苯, 对溴苯甲醇
质量水平
方案
99%
表单
solid
mp
75-77 °C (lit.)
溶解性
dioxane: soluble 1 g/10 mL, clear to faintly turbid, colorless to faintly yellow
官能团
bromo
hydroxyl
SMILES字符串
OCc1ccc(Br)cc1
InChI
1S/C7H7BrO/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2
InChI key
VEDDBHYQWFOITD-UHFFFAOYSA-N
基因信息
human ... ALOX12(239), ALOX15(246)
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一般描述
4-溴苯甲醇与乙酰基二茂铁和芳基硼酸发生三组分反应，生成含有联芳基的二茂铁酮 。它在聚乙烯聚吡咯烷酮负载的过氧化氢、二氧化硅硫酸和溴化铵存在下发生氧化反应，生成 4-溴苯甲醛 。它与 1,1,1,3,3,3-六甲基二硅氮烷在催化剂量的天冬氨酸乙腈溶液中发生有效的三甲基硅烷化反应 。
应用
使用 4-溴苄醇合成：
- 羟基末端功能化、取代聚芴
- 聚（9,9-二十二烷基芴-2,7-二基）和聚（甲基丙烯酸羟乙酯）的三嵌段共聚物，对称棒状线圈
危险声明
预防措施声明
危险分类
Aquatic Chronic 3
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
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