187240
9-蒽甲醇
97%
别名:
9-(羟甲基)蒽
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关于此项目
经验公式（希尔记法）:
C15H12O
化学文摘社编号:
分子量:
208.26
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
215-998-5
Beilstein/REAXYS Number:
1873402
MDL number:
Assay:
97%
Quality Level
assay
97%
solubility
chloroform: soluble 20 mg/mL, clear to slightly hazy, light yellow to yellow
functional group
hydroxyl
SMILES string
OCc1c2ccccc2cc3ccccc13
InChI
1S/C15H12O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9,16H,10H2
InChI key
JCJNNHDZTLRSGN-UHFFFAOYSA-N
General description
9-蒽甲醇参与由氧化铝烷催化的L-丙交酯的开环聚合反应。它与叔-丁醇钾发生质子交换反应，生成9-蒽甲醇。
9-蒽甲醇是蒽的衍生物，常用于Diels-Alder反应。
9-蒽甲醇是蒽的衍生物，常用于Diels-Alder反应。
Application
9-蒽甲醇可用于：
- 作为制备9-蒽甲基-1-哌嗪羧酸酯的起始原料，充当HPLC测定异氰酸酯的试剂。
- Diels-Alder 反应,与二甲基乙炔-二羧酸酯反应生成内酯衍生物。
- 作为δ-戊内酯开环聚合反应引发剂，合成聚（(δ-戊内酯)。
- 作为合成聚合物载体蒽的起始材料，在环加成反应中充当亲二烯体清除剂。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Development of a new approach for total isocyanate determination using the reagent 9-anthracenylmethyl-1-piperazinecarboxylate.
Roh Y-M, et al.
Analyst, 125(9), 1691-1696 (2000)
Cyclodextrin-promoted Diels Alder reactions of a polycyclic aromatic hydrocarbon under mild reaction conditions
Chaudhuri, et al.
Tetrahedron Letters, 56, 1619-1623 (2015)
J W Flesher et al.
Biochemical and biophysical research communications, 251(1), 239-243 (1998-10-29)
The role of electrophilic hydroxymethyl sulfate esters in the metabolic activation, DNA-damage, mutagenicity, and complete carcinogenicity of polycyclic aromatic hydrocarbons has been elucidated considerably in recent years. The observations are in agreement with a unified hypothesis which predicts that electrophilic
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 187240-5G | 04061838758477 |
| 187240-10G | 04061838758453 |
| 187240-50G | 04061838758460 |