189022
2-甲基-2-硝基丙烷
99%
别名:
1,1-Dimethyl-1-nitroethane, 2-Methyl-2-nitropropane, 2-Nitro-2-methylpropane, 2-Nitroisobutane, Trimethylnitromethane
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关于此项目
线性分子式:
(CH3)3CNO2
化学文摘社编号:
分子量:
103.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
209-851-4
MDL number:
Assay:
99%
InChI key
AIMREYQYBFBEGQ-UHFFFAOYSA-N
InChI
1S/C4H9NO2/c1-4(2,3)5(6)7/h1-3H3
SMILES string
CC(C)(C)[N+]([O-])=O
assay
99%
refractive index
n20/D 1.4 (lit.)
bp
126-127 °C (lit.)
density
0.95 g/mL at 25 °C (lit.)
functional group
amine, nitro
Quality Level
General description
Photodissociation of 2-methyl-2-nitropropane at 193 and 248nm leads to the formation of OH fragment and electronically excited NO2. Hydrolysis reaction of 2-methyl-2-nitropropane in the presence of platinum-alumina catalyst yields N2O.
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
66.2 °F - closed cup
flash_point_c
19 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
N2O formation during organic nitro compounds' hydrolysis on platinum based catalysts.
Joubert E, et al.
Applied Catalysis. B, Environmental, 23(2), L83-L87 (1999)
Sumana Sengupta et al.
The journal of physical chemistry. A, 112(49), 12572-12581 (2008-12-05)
Dynamics of formation of electronically excited NO2 and formation of OH fragment, during photo dissociation of 2-nitropropane (NP) and 2-methyl-2-nitropropane (MNP), were investigated at 193 and 248 nm. The radiative lifetime of the electronically excited NO2 fragment, observed at 193
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