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Merck
CN

189219

氯灭鼠灵

98%

别名:

(±)-3-(α-丙酮基-对氯苄基)-4-羟基香豆素, 氯华法令

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关于此项目

经验公式(希尔记法):
C19H15ClO4
化学文摘社编号:
分子量:
342.77
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-378-1
Beilstein/REAXYS Number:
6819431
MDL number:
Assay:
98%
Form:
powder
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InChI key

DEKWZWCFHUABHE-UHFFFAOYSA-N

InChI

1S/C19H15ClO4/c1-11(21)10-15(12-6-8-13(20)9-7-12)17-18(22)14-4-2-3-5-16(14)24-19(17)23/h2-9,15,22H,10H2,1H3

SMILES string

CC(=O)CC(c1ccc(Cl)cc1)C2=C(O)c3ccccc3OC2=O

assay

98%

form

powder

mp

168-170 °C (lit.)

solubility

acetone: soluble, alcohol: soluble, benzene: slightly soluble, chloroform: soluble, diethyl ether: slightly soluble, water: insoluble

functional group

chloro, ester, ketone

General description

Coumachlor is an anticoagulant rodenticide. It forms complex with zirconium.

Application

Coumachlor was used as internal standard for simultaneous enantioseparation of (+/-)-warfarin by chiral capillary electrochromatography with electrospray ionization mass spectrometry.

pictograms

Skull and crossbonesHealth hazard

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - STOT RE 2

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jack Zheng et al.
Analytical chemistry, 75(22), 6295-6305 (2003-11-18)
The hyphenation of chiral capillary electrochromatography (CEC) with electrospray ionization mass spectrometry (ESI-MS) is very challenging but promising due to the fact that it combines sensitivity with high specificity and selectivity. In this work, CEC capillaries packed with (3R,4S)-Whelk-O1 chiral
Jakob Avi Shimshoni et al.
Journal of veterinary diagnostic investigation : official publication of the American Association of Veterinary Laboratory Diagnosticians, Inc, 25(6), 736-743 (2013-10-02)
Anticoagulant rodenticides are frequently a cause of poisoning of domestic animals, wildlife, and human beings. A toxicosis in 6,000 laying hens caused by the malicious addition of unknown amounts of coumatetralyl bait as well as the insecticides aldicarb, methomyl, and
L A Svensson et al.
The Analyst, 125(6), 1037-1039 (2000-08-10)
Racemic mixtures of five acidic drugs have been successfully separated by supercritical fluid chromatography (SFC) using macrocyclic antibiotic chiral stationary phases (CSPs). A ristocetin A CSP has been prepared 'in-house' and effectively applied in packed capillary SFC to separate the
Wenjian Lao et al.
Journal of chromatography. A, 1217(42), 6545-6554 (2010-09-18)
Unusual peak profiles of warfarin were characterized on two oligoproline chiral stationary phases (CSPs). The pattern of 1st peak (S(-)) broadening and the 2nd peak (R(+)) compression was observed under mobile phase of hexane (0.1% TFA)/2-propanol (IPA) on a triproline
Jack Zheng et al.
Journal of chromatography. A, 1005(1-2), 177-187 (2003-08-20)
The capillary electrochromatographic separations of three acidic enantiomers (carprofen, coumachlor and warfarin) were studied on a capillary column packed with 5 microm (3R,4S)-Whelk-O 1 chiral stationary phase. The influence of several experimental parameters (mobile phase pH, type of background electrolyte

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