189316
3-氯-2,2-二甲基-1-丙醇
99%
别名:
2-氯甲基-2-甲基-1-丙醇
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关于此项目
线性分子式:
ClCH2C(CH3)2CH2OH
化学文摘社编号:
分子量:
122.59
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
99%
折射率
n20/D 1.45 (lit.)
沸点
87 °C/35 mmHg (lit.)
mp
34-36 °C (lit.)
官能团
chloro
hydroxyl
SMILES字符串
CC(C)(CO)CCl
InChI
1S/C5H11ClO/c1-5(2,3-6)4-7/h7H,3-4H2,1-2H3
InChI key
CAZPRAORHCOIHC-UHFFFAOYSA-N
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一般描述
3-Chloro-2,2-dimethyl-1-propanol undergoes oxidation with pyridinium chlorochromate to yield 3-chloro-2,2-dimethylpropanal which spontaneously trimerizes to s-trioxane.
应用
3-Chloro-2,2-dimethyl-1-propanol has been used in combinatorial preparation of new aroma-impact compounds such as polyfunctional thiols.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
159.8 °F - closed cup
闪点(°C)
71 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
2, 4, 6-Tri (2'-chloro-1', 1'-dimethylethyl)-s-trioxane: Synthesis, Spectroscopy and Crystal Structure.
Tarbutton GL and Valente EJ.
Journal of Chemical Crystallography, 40(2), 126-129 (2010)
Catherine Vermeulen et al.
Combinatorial chemistry & high throughput screening, 9(8), 583-590 (2006-10-05)
Combinatorial chemistry was shown to be an efficient tool for the preparation of new aroma-impact compounds. In this case, polyfunctional thiols were synthesized quickly using halide reagents or Bunte salt intermediates. They were separated by gas chromatography and then characterized
Xin Min et al.
Royal Society open science, 5(5), 180156-180156 (2018-06-13)
A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized. By using TBDMSODPrLi, hydroxyl-terminated polybutadiene (HTPB) was prepared via anionic polymerization. The macromolecular structure of HTPB was characterized and verified by FTIR and
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