190144
氯铬酸吡啶盐
98%
别名:
PCC
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关于此项目
线性分子式:
C5H6NClCrO3
化学文摘社编号:
分子量:
215.56
Beilstein:
7054643
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
98%
表单
solid
反应适用性
reagent type: oxidant
mp
205-208 °C (lit.)
SMILES字符串
O[Cr](Cl)(=O)=O.c1ccncc1
InChI
1S/C5H5N.ClH.Cr.H2O.2O/c1-2-4-6-5-3-1;;;;;/h1-5H;1H;;1H2;;/q;;+2;;;/p-2
InChI key
JWIPGAFCGUDKEY-UHFFFAOYSA-L
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一般描述
PCC是一种重要的有机试剂，用于氧化反应。
应用
用于由 D-葡萄糖经 Grubbs 催化闭环复分解反应合成 α,ß-不饱和内酯过程中氧化烯丙基亚甲基。
稳定的多功能氧化剂，用于醇类的温和选择性氧化。
警示用语：
Danger
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Ox. Sol. 2 - Skin Sens. 1
储存分类代码
5.1B - Oxidizing hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Recent advances in application of pyridinium chlorochromate (PCC) in organic synthesis
M Heravi M, et al.
Current Organic Synthesis, 13(2), 220-254 (2016)
Perrine Ferré et al.
Language, cognition and neuroscience, 34(8), 949-972 (2019-08-29)
Most of the current knowledge about age-related differences in brain neurofunctional organization stems from neuroimaging studies using either a "resting state" paradigm, or cognitive tasks for which performance decreases with age. However, it remains to be known if comparable age-related
Tetrahedron, 62, 11165-11165 (2006)
Anna M Larsson et al.
Journal of experimental botany, 68(14), 3857-3867 (2017-04-04)
Cyanobacterial CO2 fixation is promoted by encapsulating and co-localizing the CO2-fixing enzymes within a protein shell, the carboxysome. A key feature of the carboxysome is its ability to control selectively the flux of metabolites in and out of the shell.
Cheryl Peters et al.
Pediatric critical care medicine : a journal of the Society of Critical Care Medicine and the World Federation of Pediatric Intensive and Critical Care Societies, 19(8), e394-e402 (2018-06-26)
We evaluated adapting the quick Sequential (Sepsis-Related) Organ Failure Assessment score (fast respiratory rate, altered mental status, low blood pressure) for pediatric use by selecting thresholds from three commonly used definitions: Pediatric Logistic Organ Dysfunction 2, Pediatric Advanced Life Support
商品
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
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