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Merck
CN

190144

Sigma-Aldrich

氯铬酸吡啶盐

98%

别名:

PCC

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关于此项目

线性分子式:
C5H6NClCrO3
CAS Number:
分子量:
215.56
Beilstein:
7054643
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

98%

表单

solid

反应适用性

reagent type: oxidant

mp

205-208 °C (lit.)

SMILES字符串

O[Cr](Cl)(=O)=O.c1ccncc1

InChI

1S/C5H5N.ClH.Cr.H2O.2O/c1-2-4-6-5-3-1;;;;;/h1-5H;1H;;1H2;;/q;;+2;;;/p-2

InChI key

JWIPGAFCGUDKEY-UHFFFAOYSA-L

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一般描述

PCC是一种重要的有机试剂,用于氧化反应。

应用

用于由 D-葡萄糖经 Grubbs 催化闭环复分解反应合成 α,ß-不饱和内酯过程中氧化烯丙基亚甲基。
稳定的多功能氧化剂,用于醇类的温和选择性氧化。

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Ox. Sol. 2 - Skin Sens. 1

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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J Nwando Olayiwola et al.
Journal of telemedicine and telecare, 25(8), 493-498 (2018-07-12)
Electronic consultations (eConsults) provide asynchronous, store-and-forward communication between primary care clinicians (PCCs) and specialists using web-based platforms, electronic health records or mobile applications. eConsults have demonstrated benefits in many areas of the Quadruple Aim, including educational value for PCCs. In
Atul Verma et al.
JAMA surgery, 153(6), 577-585 (2018-05-02)
Non-vitamin K oral anticoagulants (NOACs) are increasingly prescribed for patients to treat or prevent arterial or venous thromboembolism. The following 4 NOAC agents are approved by the US Food and Drug Administration for clinical use: dabigatran etexilate, apixaban, edoxaban tosylate
Xueling Zhu et al.
Scientific reports, 7, 43105-43105 (2017-02-23)
Neuroimaging evidence implicates the association between rumination and default mode network (DMN) in major depressive disorder (MDD). However, the relationship between rumination and DMN subsystems remains incompletely understood, especially in patients with MDD. Thirty-three first-episode drug-naive patients with MDD and
L Jordaens et al.
Reproduction (Cambridge, England), 153(6), 759-773 (2017-03-05)
We hypothesized that elevated non-esterified fatty acids (NEFA) modify
Perrine Ferré et al.
Language, cognition and neuroscience, 34(8), 949-972 (2019-08-29)
Most of the current knowledge about age-related differences in brain neurofunctional organization stems from neuroimaging studies using either a "resting state" paradigm, or cognitive tasks for which performance decreases with age. However, it remains to be known if comparable age-related

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Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

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