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Merck
CN

191744

3-甲基-1-苯基-2-磷 1-氧化物

85%, technical grade

别名:

1-氧代-3-甲基-1-苯基-2-磷烯, 2,3-二氢-4-甲基-1-苯磷-1-氧化物, MPPO, NSC 107634

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关于此项目

经验公式（希尔记法）:
C11H13OP
化学文摘社编号:
707-61-9
分子量:
192.19
NACRES:
NA.22
PubChem Substance ID:
24851507
UNSPSC Code:
12352005
MDL number:
MFCD00014518

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产品名称

3-甲基-1-苯基-2-磷 1-氧化物, 85%, technical grade

InChI

1S/C11H13OP/c1-10-7-8-13(12,9-10)11-5-3-2-4-6-11/h2-6,9H,7-8H2,1H3

SMILES string

CC1=CP(=O)(CC1)c2ccccc2

InChI key

YMKWWHFRGALXLE-UHFFFAOYSA-N

grade

technical grade

assay

85%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

impurities

5% dichloromethane

refractive index

n20/D 1.5707 (lit.)

bp

150 °C/0.15 mmHg (lit.)

Application

用于催化：
  • 分子内 aza-Wittig 环化反应
  • 聚合反应

反应物用于制备：
  • 抗癌磷糖及其溴化衍生物

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBJ3879V
MKBD1485V
MKBD1485
MKBC7521
MKBD0376

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Phuong-Mai Nguyen et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 34(10), 1703-1720 (2017-04-05)
Migration due to indirect contact with packaging caused several major sanitary crises, including the spread contamination of dry food by mineral oils and printing ink constituents from cardboard. The issues are still not fully resolved because the mechanisms have been
Andrea Walzl et al.
Molecules (Basel, Switzerland), 25(15) (2020-08-06)
The current demand to cut back on the use of plastic materials has brought a major boost to the search for bio-based alternatives. Not only are plastic bags and primary food packaging under scrutiny here, but also those materials used

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