192201
2,4,6-三甲基苯磺酰肼
97%
别名:
2-均三甲苯磺酰肼
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关于此项目
线性分子式:
(CH3)3C6H2SO2NHNH2
化学文摘社编号:
分子量:
214.28
Beilstein:
2118380
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
mp
112-114 °C (dec.) (lit.)
官能团
hydrazine
SMILES字符串
Cc1cc(C)c(c(C)c1)S(=O)(=O)NN
InChI
1S/C9H14N2O2S/c1-6-4-7(2)9(8(3)5-6)14(12,13)11-10/h4-5,11H,10H2,1-3H3
InChI key
JQUBKTQDNVZHIY-UHFFFAOYSA-N
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应用
2,4,6-Trimethylbenzenesulfonohydrazide has been used in the synthesis of:
- (E)-N′-(1-((1S*,4aR*,8aR*)-1-hydroxydecahydronaphthalen-4a-yl)ethylidene)-2,4,6-trimethylbenzenesulfonohydrazide
- complanadine alkaloids
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
4.1B - Flammable solid hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Concise Synthesis of 1, 4a-Bifunctionalised Decalin Building Blocks by CH Activation of Decalin.
Uosis-Martin M, et al.
Synlett, 2011(15), 2211-2213 (2011)
Mario Uosis-Martin et al.
The Journal of organic chemistry, 78(12), 6253-6263 (2013-05-30)
A synthetic approach to complanadine alkaloids is described which employs a Kondrat'eva reaction to construct the pyridine rings. The viability of this approach is demonstrated by its application to a model substrate accessed from unfunctionalized decalin. The key transformation affords
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