193925
4-甲基噻唑
99%
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关于此项目
经验公式（希尔记法）:
C4H5NS
化学文摘社编号:
分子量:
99.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
211-764-1
MDL number:
Assay:
99%
Form:
liquid
InChI key
QMHIMXFNBOYPND-UHFFFAOYSA-N
InChI
1S/C4H5NS/c1-4-2-6-3-5-4/h2-3H,1H3
SMILES string
Cc1cscn1
assay
99%
form
liquid
refractive index
n20/D 1.524 (lit.)
bp
133-134 °C (lit.)
density
1.09 g/mL at 25 °C (lit.)
Quality Level
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General description
4-甲基噻唑与钴(II)、锌(II)、镍(II)和铜(II)卤化物形成络合物。
Application
4-甲基噻唑被用于合成催化的dendrophanes，作为硫胺二磷酸依赖性酶丙酮酸氧化酶的功能模拟物。它被用于3-丁基-4-甲基噻唑鎓溴化物的小规模制备。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
89.6 °F - closed cup
flash_point_c
32 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Shivaji H Shelke et al.
Bioorganic & medicinal chemistry letters, 22(20), 6373-6376 (2012-09-18)
A new series of 3-aryl-2-(2-aryl/benzyl-4-methylthiazole-5-yl)thiazolidin-4-one was synthesized by condensation of 2-aryl/benzyl-4-methylthiazole-5-carbaldehyde, aromatic amines and thioglycolic acid in toluene. All the synthesized compounds are characterized by IR, NMR and elemental or mass analysis. Sixteen out of the newly synthesized compounds were
Sarah E O'Connor et al.
Biochemistry, 41(17), 5685-5694 (2002-04-24)
The biosynthesis of epothilones, a family of hybrid polyketide (PK)/nonribosomal peptide (NRP) antitumor agents, provides an ideal system to study a hybrid PK/NRP natural product with significant biomedical value. Here the third enzyme involved in epothilone production, the five domain
Metal complexes of 4-methylthiazole.
Hughes MN and Rutt KJ.
Inorganic Chemistry, 10(2), 414-416 (1971)
Improved preparations of ionic liquids using microwave irradiation.
Deetlefs M and Seddon KR.
Green Chemistry, 5(2), 181-186 (2003)
Catalytic Dendrophanes as Enzyme Mimics: Synthesis, Binding Properties, Micropolarity Effect, and Catalytic Activity of Dendritic Thiazolio-cyclophanes.
Habicher T, et al.
Helvetica Chimica Acta, 82(7), 1066-1095 (1999)
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