194328
3-甲基-2-丁烯酸乙酯
98%
别名:
3-甲基丁烯酸乙酯
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关于此项目
线性分子式:
(CH3)2C=CHCO2C2H5
化学文摘社编号:
分子量:
128.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
211-319-1
MDL number:
Assay:
98%
Form:
liquid
产品名称
3-甲基-2-丁烯酸乙酯, 98%
InChI key
UTXVCHVLDOLVPC-UHFFFAOYSA-N
InChI
1S/C7H12O2/c1-4-9-7(8)5-6(2)3/h5H,4H2,1-3H3
SMILES string
CCOC(=O)\C=C(\C)C
assay
98%
form
liquid
refractive index
n20/D 1.436 (lit.)
bp
154-155 °C (lit.)
density
0.922 g/mL at 25 °C (lit.)
functional group
ester
Quality Level
Application
Ethyl 3,3-dimethylacrylate was used in the synthesis of:
- 3-benzylmercupto-3-methylbutanoic acid ethylester
- cis-2-cyano-3,3-dimethylcyclopropanecarboxylic acid, precursor for the synthesis of cis-pyrethroids
- 1-[13CD3]-9-cis-retinoic acid
General description
Ion-molecule reactions between the O=P(OCH3)2+phosphonium ions and ethyl 3,3-dimethylacrylate has been investigated by quadrupole ion trap mass spectrometery.
Potent odorants of the roasted powder and brew of Arabica coffee.
Blank I, et al.
Zeitschrift fur Lebensmittel-Untersuchung Und -Forschung, 195(3), 239-245 (1992)
[Toxicological characteristics and the establishment of a MPEL for dimethylacrylic acid and its ethyl ether in the air of a work area].
A I Gurova et al.
Gigiena truda i professional'nye zabolevaniia, (4)(4), 52-53 (1985-04-01)
Synthesis of 1-[13CD3]-9-cis-retinoic acid.
Bennani YL
Journal of Labelled Compounds & Radiopharmaceuticals, 36(8), 755-763 (1995)
A facile route to a versatile synthon for preparation of cis-pyrethroids.
Babler JH and Invergo BJ.
Tetrahedron Letters, 22(29), 2743-2746 (1981)
Eric Leclerc et al.
Journal of mass spectrometry : JMS, 40(4), 458-463 (2005-02-16)
Ion-molecule reactions between the O=P(OCH3)2 + phosphonium ions and eight alpha,beta-unsaturated esters (methyl acrylate, ethyl acrylate, methyl crotonate, ethyl crotonate, methyl 3,3-dimethylacrylate, ethyl 3,3-dimethylacrylate, methyl methacrylate and ethyl methacrylate) were performed in a quadrupole ion trap mass spectrometer. The O=P(OCH3)2
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