194387
克霉唑杂质E
≥99%
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关于此项目
线性分子式:
ClC6H4COC6H5
化学文摘社编号:
分子量:
216.66
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
225-936-9
MDL number:
Assay:
≥99%
产品名称
克霉唑杂质E, ≥99%
InChI key
VMHYWKBKHMYRNF-UHFFFAOYSA-N
InChI
1S/C13H9ClO/c14-12-9-5-4-8-11(12)13(15)10-6-2-1-3-7-10/h1-9H
SMILES string
Clc1ccccc1C(=O)c2ccccc2
assay
≥99%
bp
330 °C (lit.)
mp
44-47 °C (lit.)
functional group
chloro
ketone
phenyl
Quality Level
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Application
2-Chlorobenzophenone was used in the synthesis of 1-(2-chlorophenyl)isoquinolin-3-yl trifluoromethanesulfonate.
General description
Thermodynamics of formation of inclusion complex between 2-chlorobenzophenone and cyclomaltoheptaose (β-cyclodextrin) has been investigated by UV-vis spectroscopy and reversed-phase liquid chromatography. 2-Chlorobenzophenone undergoes reduction in the presence of LiAlH4 and (R)-(-)-2-(2-iso-indolinyl)butan-1-ol to afford the corresponding benzhydrols.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Matias I Sancho et al.
Carbohydrate research, 346(13), 1978-1984 (2011-06-07)
A thermodynamic study of the inclusion process between 2-chlorobenzophenone (2ClBP) and cyclomaltoheptaose (β-cyclodextrin, β-CD) was performed using UV-vis spectroscopy, reversed-phase liquid chromatography (RP-HPLC), and molecular modeling (PM6). Spectrophotometric measurements in aqueous solutions were performed at different temperatures. The stoichiometry of
Asymmetric reductions of ketones using lithium aluminium hydride modified with N, N-dialkyl derivatives of (R)-(-)-2-aminobutan-1-ol.
Brown E, et al.
Tetrahedron Asymmetry, 2(5), 339-342 (1991)
Synthesis of N-methyl-N-(1-methylpropyl)-1-(2-chlorophenyl) isoquinoline-3-[11 C] carboxamide ([11 C-carbonyl] PK11195) and some analogues using [11 C] carbon monoxide and 1-(2-chlorophenyl) isoquinolin-3-yl triflate.
Rahman O, et al.
Journal of the Chemical Society. Perkin Transactions 1, 23, 2699-2703 (2002)
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