194409
溴三甲基硅烷
97%
别名:
TMBS, 三甲基溴化硅, 三甲基溴硅烷
质量水平
方案
97%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.424 (lit.)
沸点
79 °C (lit.)
密度
1.16 g/mL at 25 °C (lit.)
SMILES字符串
C[Si](C)(C)Br
InChI
1S/C3H9BrSi/c1-5(2,3)4/h1-3H3
InChI key
IYYIVELXUANFED-UHFFFAOYSA-N
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应用
与 InCl3 共同用于催化用烯丙基三甲基硅烷直接烯丙基化各种醇。
警示用语：
Danger
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
89.6 °F
闪点(°C)
32 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Takahiro Saito et al.
The Journal of organic chemistry, 71(22), 8516-8522 (2006-10-27)
The combination of InCl3 and Me3SiBr provided an enhanced Lewis acid system that can be used to promote a wide range of direct coupling reactions between alcohols and silyl nucleophiles in non-halogenated solvents, such as hexane or MeCN. The enhanced
J. Chem. Soc. Perkin Trans. II, 263-263 (1991)
Aldrichimica Acta, 14, 31-31 (1981)
Tetrahedron Letters, 34, 7713-7713 (1993)
J A Robl et al.
Journal of medicinal chemistry, 34(9), 2804-2815 (1991-09-11)
A series of 2,3,4,(5),6-substituted pyridines containing a hydroxyphosphinyl functionally have been prepared and were evaluated for their ability to inhibit the enzyme HMG-CoA reductase. Systematic substitution of both R1-R4 and X-Y led to compounds of type 3-6 with in vitro
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