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文件

195332

1-溴十四烷

Name: 1-溴十四烷
Brand: ALDRICH

97%

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别名:

十四烷基溴, 肉豆蔻基溴

线性分子式:

CH₃(CH₂)₁₃Br

CAS号:

112-71-0

分子量:

277.28

Beilstein:

1742640

EC 号:

203-999-3

MDL编号:

MFCD00000228

PubChem化学物质编号:

24851686

NACRES:

NA.22

质量水平

200

检测方案

97%

形式

liquid

折射率

n20/D 1.460 (lit.)

bp

175-178 °C/20 mmHg (lit.)

mp

5-6 °C (lit.)

密度

0.932 g/mL at 25 °C (lit.)

SMILES字符串

CCCCCCCCCCCCCCBr

InChI

1S/C14H29Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h2-14H2,1H3

InChI key

KOFZTCSTGIWCQG-UHFFFAOYSA-N

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应用

1-溴十四烷可用于合成：

十四烷基二茂铁
阳离子和两性离子双子表面活性剂
基于双[η¹(N)-3,4-二烷氧基亚苄基-4′-十二烷基氧基苯胺]二氯钯 (II) 的带有辛基、癸基、十二烷基、十四烷基和十六烷基烷基的金属配位聚合物
9-十四烷基咔唑

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Novel Metallomesogenic Polymers Derived from ? 1-Benzylideneaniline Palladium (II) Complex.

Lee M, et al.

Macromolecules, 32(8), 2777-2782 (1999)

Tetradecylferrocene: ordered molecular array of an organometallic amphiphile in the crystal and in a two-dimensional assembled structure on a surface.

Katrin Wedeking et al.

Langmuir : the ACS journal of surfaces and colloids, 22(7), 3161-3165 (2006-03-22)

Tetradecylferrocene (4, Fc-(CH2)13CH3) was synthesized via lithiation of ferrocene by treatment with tert-butyl lithium, followed by alkylation with 1-bromotetradecane. Complex 4 forms a physisorbed ordered molecular monolayer on the surface of highly oriented pyrolytic graphite (HOPG) that was analyzed by

Poly(Ionic Liquid) Nanoparticles Selectively Disrupt Biomembranes.

Eleanor Ewins et al.

Advanced science (Weinheim, Baden-Wurttemberg, Germany), 6(4), 1801602-1801602 (2019-03-05)

Polymer-based nanoparticles have an increasing presence in research due to their attractive properties, such as flexible surface functionality design and the ability to scale up production. Poly(ionic liquid) (PIL) nanoparticles of size below 50 nm are very unique in terms

Preparation of a Carbazole-Based Macrocycle Via Precipitation-Driven Alkyne Metathesis.

Zhang W, et al.

Organic Syntheses, 177-191 (2007)

Experimental and Theoretical Study on Supramolecular Ionic Liquid (IL)-Asphaltene Complex Interactions and Their Effects on the Flow Properties of Heavy Crude Oils.

R Hernández-Bravo et al.

The journal of physical chemistry. B, 122(15), 4325-4335 (2018-03-29)

A combined study for understanding the molecular interactions of asphaltenes with molecular species such as ionic liquids (ILs) comprised experimental measurements and computational numerical simulation calculations, using density-functional theory (DFT) with dispersion corrections, molecular dynamics (MD) calculations, and experimental rheological

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