195731
五羰基铁
别名:
五羰基铁, 羰基铁
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关于此项目
线性分子式:
Fe(CO)5
化学文摘社编号:
分子量:
195.90
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
蒸汽密度
6.74 (vs air)
质量水平
蒸汽压
35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)
自燃温度
122 °F
反应适用性
core: iron
reagent type: catalyst
环保替代产品特性
Catalysis
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折射率
n20/D 1.5196 (lit.)
沸点
103 °C (lit.)
mp
−20 °C (lit.)
密度
1.49 g/mL at 25 °C (lit.)
环保替代产品分类
, Aligned
储存温度
2-8°C
SMILES字符串
[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/5CO.Fe/c5*1-2;
InChI key
FYOFOKCECDGJBF-UHFFFAOYSA-N
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我们致力为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。 点击此处了解更多信息。
应用
五羰基铁（0）可用于：
- 作为铁源，用于合成铁掺杂的薄TiO2薄膜。
- 作为合成金（I）和Fe（CO）5以及 银和Fe（CO）5配合物的配体。
用作以下过程的反应物：
- 加成反应
- 通过光解分解
- 热分解法制备尺寸分布窄的铁洋葱状富勒烯磁性微粒
- 碳酰胺氢硅烷还原反应中七核铁羰基簇合物的制备
- 高碱性条件下制备光催化析氢 Fe 纳米粒子的前驱体
警示用语：
Danger
危险分类
Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
5.0 °F - closed cup
闪点(°C)
-15 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Brian Ahr et al.
Physical chemistry chemical physics : PCCP, 13(13), 5590-5599 (2011-01-15)
Ultrafast X-ray absorption near edge spectroscopy has been carried out for photo excited iron pentacarbonyl in ethanol with 2 picosecond resolution. A temporal resolution limited dissociation process was observed, followed by the formation of the mono-substituted complex Fe(CO)(4)EtOH within a
Li Long et al.
Dalton transactions (Cambridge, England : 2003), 41(31), 9482-9492 (2012-07-04)
Reaction of Fe(3)(CO)(12) with pyridinyl thioester ligand PyCH(2)SCOCH(3) (L(1), Py = pyridin-2-yl) produced complex, [Fe(2)(κ-COCH(3))(μ-SCH(2)Py)(CO)(5)] (1) (PyCH(2)S = pyridin-2-ylmethanethiolate). When complex 1 reacted with PPh(3), a monosubstituted complex, [Fe(2)(κ-COCH(3))(μ-SCH(2)Py)(CO)(4)PPh(3)] (2), was derived. Reaction of the same precursor with analogous thioester
S Lakshmi Devi et al.
Amino acids, 38(3), 869-879 (2009-04-22)
Taurine effectively prevents ischemia-induced apoptosis in the cardiomyocytes and hypothalamic nuclei. The present study explores the influence of taurine on mitochondrial damage, oxidative stress and apoptosis in experimental liver fibrosis. Male albino Wistar rats were divided into six groups and
Bianca Seminotti et al.
International journal of developmental neuroscience : the official journal of the International Society for Developmental Neuroscience, 26(7), 693-698 (2008-08-12)
The present work investigated the in vitro effects of lysine on important parameters of oxidative stress in cerebral cortex of young rats. Our results show that lysine significantly induced lipid peroxidation, as determined by increase of thiobarbituric acid-reactive substances and
Victoria N Tsupreva et al.
Inorganic chemistry, 50(8), 3325-3331 (2011-03-17)
Interaction of the copper, {[3,5-(CF(3))(2)Pz]Cu}(3), and silver, {[3,5-(CF(3))(2)Pz]Ag}(3), macrocycles [3,5-(CF(3))(2)Pz = 3,5-bis(trifluoromethyl)pyrazolate] with cyclooctatetraeneiron tricarbonyl, (cot)Fe(CO)(3), was investigated by IR and NMR spectroscopy for the first time. The formation of 1:1 complexes was observed at low temperatures in hexane. The
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