195731
五羰基铁
别名:
五羰基铁, 羰基铁
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关于此项目
线性分子式:
Fe(CO)5
化学文摘社编号:
分子量:
195.90
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
236-670-8
MDL number:
InChI key
FYOFOKCECDGJBF-UHFFFAOYSA-N
InChI
1S/5CO.Fe/c5*1-2;
SMILES string
[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
vapor density
6.74 (vs air)
vapor pressure
35 mmHg ( 25 °C), 40 mmHg ( 30.3 °C)
autoignition temp.
122 °F
reaction suitability
core: iron, reagent type: catalyst
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
refractive index
n20/D 1.5196 (lit.)
bp
103 °C (lit.)
mp
−20 °C (lit.)
density
1.49 g/mL at 25 °C (lit.)
greener alternative category
, Aligned
storage temp.
2-8°C
Quality Level
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General description
我们致力为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。 点击此处了解更多信息。
Application
五羰基铁（0）可用于：
- 作为铁源，用于合成铁掺杂的薄TiO2薄膜。
- 作为合成金（I）和Fe（CO）5以及 银和Fe（CO）5配合物的配体。
用作以下过程的反应物：
- 加成反应
- 通过光解分解
- 热分解法制备尺寸分布窄的铁洋葱状富勒烯磁性微粒
- 碳酰胺氢硅烷还原反应中七核铁羰基簇合物的制备
- 高碱性条件下制备光催化析氢 Fe 纳米粒子的前驱体
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
5.0 °F - closed cup
flash_point_c
-15 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Victoria N Tsupreva et al.
Inorganic chemistry, 50(8), 3325-3331 (2011-03-17)
Interaction of the copper, {[3,5-(CF(3))(2)Pz]Cu}(3), and silver, {[3,5-(CF(3))(2)Pz]Ag}(3), macrocycles [3,5-(CF(3))(2)Pz = 3,5-bis(trifluoromethyl)pyrazolate] with cyclooctatetraeneiron tricarbonyl, (cot)Fe(CO)(3), was investigated by IR and NMR spectroscopy for the first time. The formation of 1:1 complexes was observed at low temperatures in hexane. The
Bianca Seminotti et al.
International journal of developmental neuroscience : the official journal of the International Society for Developmental Neuroscience, 26(7), 693-698 (2008-08-12)
The present work investigated the in vitro effects of lysine on important parameters of oxidative stress in cerebral cortex of young rats. Our results show that lysine significantly induced lipid peroxidation, as determined by increase of thiobarbituric acid-reactive substances and
John T Tsalavoutis et al.
Journal of computational chemistry, 31(10), 1969-1978 (2010-01-21)
The equilibrium structures and vibrational frequencies of the iron complexes [Fe(0)(CN)(n)(CO)(5-n)](n-) and [Fe(II)(CN)(n)(CO)(5-n)](2-n) (n = 0-5) have been calculated at the BP86 level of theory. The Fe(0) complexes adopt trigonal bipyramidal structures with the cyano ligands occupying the axial positions
Anders Bergh et al.
Carbohydrate research, 343(10-11), 1808-1813 (2008-05-13)
Cationic iron carbonyl cyclohexadiene complexes were employed in the derivatization of the 3-OH position of unprotected and protected methyl beta-D-galactopyranosides using two different approaches, giving access to galactopyranosides with an aromatic or cyclohexadienoic functionality in this position.
S Lakshmi Devi et al.
Amino acids, 38(3), 869-879 (2009-04-22)
Taurine effectively prevents ischemia-induced apoptosis in the cardiomyocytes and hypothalamic nuclei. The present study explores the influence of taurine on mitochondrial damage, oxidative stress and apoptosis in experimental liver fibrosis. Male albino Wistar rats were divided into six groups and
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