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196274

硫代吗啉

Name: 硫代吗啉
Brand: ALDRICH

98%

别名:

四氢-2H-1,4-噻嗪, 巯基吗啉

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关于此项目

经验公式（希尔记法）:

C₄H₉NS

化学文摘社编号:

123-90-0

分子量:

103.19

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24851748

EC Number:

204-660-2

Beilstein/REAXYS Number:

102550

MDL number:

MFCD00005974

Assay:

98%

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属性

Quality Level

100

assay

98%

refractive index

n20/D 1.538 (lit.)

bp

169 °C (lit.)

solubility

organic solvents: miscible(lit.), water: miscible(lit.)

density

1.026 g/mL at 25 °C (lit.)

functional group

thioether

SMILES string

C1CSCCN1

InChI

1S/C4H9NS/c1-3-6-4-2-5-1/h5H,1-4H2

InChI key

BRNULMACUQOKMR-UHFFFAOYSA-N

说明

General description

硫代吗啉与 Cu (II)、Pt (II) 和 Ni (II) 盐反应生成复合物，并对其催化活性进行了研究。

Application

硫代吗啉已经被用于制备：

N-Boc-α-烷基-β-（仲-氨基）丙氨酸
硫代吗啉- N -硼烷

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 + P310 - P501

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis and comparative reactivity of thiomorpholine-borane: aqueous hydrolysis and oxidation by hypochlorite.

Amezcua CA, et al.

Inorgorganica Chimica Acta, 290(1), 80-85 (1999)

Complexation, thermal and catalytic studies of N-substituted piperazine, morpholine and thiomorpholine with some metal ions.

Mesut Kacan et al.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 572-577 (2013-10-05)

Several Cu(II), Pt(II) and Ni(II) complexes of N-substituted, piperazine (NN donor), morpholine (NO donor) and thiomorpholine (NS donor) derivatives were synthesized and their thermal behavior and catalytic activity in epoxidation reaction of cis-diphenylethylene were studied using oxygen sources NaOCl. The

Acetylenic TACE inhibitors. Part 3: Thiomorpholine sulfonamide hydroxamates.

J I Levin et al.

Bioorganic & medicinal chemistry letters, 16(6), 1605-1609 (2006-01-24)

A series of thiomorpholine sulfonamide hydroxamate TACE inhibitors, all bearing propargylic ether P1' groups, was explored. In particular, compound 5h has excellent in vitro potency against isolated TACE enzyme and in cells, oral activity in a model of TNF-alpha production

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全球贸易项目编号

货号	GTIN
196274-25G	04061838118493
196274-5G	04061838761996