196274
硫代吗啉
98%
别名:
四氢-2H-1,4-噻嗪, 巯基吗啉
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关于此项目
经验公式（希尔记法）:
C4H9NS
化学文摘社编号:
分子量:
103.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-660-2
Beilstein/REAXYS Number:
102550
MDL number:
产品名称
硫代吗啉, 98%
InChI key
BRNULMACUQOKMR-UHFFFAOYSA-N
InChI
1S/C4H9NS/c1-3-6-4-2-5-1/h5H,1-4H2
SMILES string
C1CSCCN1
assay
98%
refractive index
n20/D 1.538 (lit.)
bp
169 °C (lit.)
solubility
organic solvents: miscible(lit.)
water: miscible(lit.)
density
1.026 g/mL at 25 °C (lit.)
functional group
thioether
Quality Level
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Application
硫代吗啉已经被用于制备：
- N-Boc-α-烷基-β-（ 仲-氨基）丙氨酸
- 硫代吗啉- N -硼烷
General description
硫代吗啉与 Cu (II)、Pt (II) 和 Ni (II) 盐反应生成复合物，并对其催化活性进行了研究 。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Synthesis and comparative reactivity of thiomorpholine-borane: aqueous hydrolysis and oxidation by hypochlorite.
Amezcua CA, et al.
Inorgorganica Chimica Acta, 290(1), 80-85 (1999)
Mesut Kacan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 572-577 (2013-10-05)
Several Cu(II), Pt(II) and Ni(II) complexes of N-substituted, piperazine (NN donor), morpholine (NO donor) and thiomorpholine (NS donor) derivatives were synthesized and their thermal behavior and catalytic activity in epoxidation reaction of cis-diphenylethylene were studied using oxygen sources NaOCl. The
J I Levin et al.
Bioorganic & medicinal chemistry letters, 16(6), 1605-1609 (2006-01-24)
A series of thiomorpholine sulfonamide hydroxamate TACE inhibitors, all bearing propargylic ether P1' groups, was explored. In particular, compound 5h has excellent in vitro potency against isolated TACE enzyme and in cells, oral activity in a model of TNF-alpha production
Upinder Singh et al.
Bioorganic & medicinal chemistry letters, 13(23), 4209-4212 (2003-11-19)
Combinatorial libraries of N-acylated 5-(S)-aminomethyloxazolidinone derivatives of S-oxide and S,S-dioxide tetrahydro-4(2H)-thiopyranyl and thiomorpholine phenyloxazolidinone series have been synthesized on a solid phase and evaluated for antimicrobial activity. Several novel potent leads have been identified, including orally active oxazolidinones with enhanced
B Beck et al.
Molecular diversity, 14(3), 479-491 (2010-04-22)
We designed two novel thiolactone scaffolds. Both scaffolds can be accessed by a convergent Ugi multicomponent reaction (MCR) and are, thus, amenable to library synthesis. Design, stereoselectivity, structures, full experimental details, and virtual libraries will be reported.
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