质量水平
方案
98%
折射率
n20/D 1.538 (lit.)
沸点
169 °C (lit.)
溶解性
organic solvents: miscible(lit.)
water: miscible(lit.)
密度
1.026 g/mL at 25 °C (lit.)
官能团
thioether
SMILES字符串
C1CSCCN1
InChI
1S/C4H9NS/c1-3-6-4-2-5-1/h5H,1-4H2
InChI key
BRNULMACUQOKMR-UHFFFAOYSA-N
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一般描述
硫代吗啉与 Cu (II)、Pt (II) 和 Ni (II) 盐反应生成复合物，并对其催化活性进行了研究 。
应用
硫代吗啉已经被用于制备：
- N-Boc-α-烷基-β-（ 仲-氨基）丙氨酸
- 硫代吗啉- N -硼烷
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
145.4 °F - closed cup
闪点(°C)
63 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Synthesis and comparative reactivity of thiomorpholine-borane: aqueous hydrolysis and oxidation by hypochlorite.
Amezcua CA, et al.
Inorgorganica Chimica Acta, 290(1), 80-85 (1999)
Mesut Kacan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 572-577 (2013-10-05)
Several Cu(II), Pt(II) and Ni(II) complexes of N-substituted, piperazine (NN donor), morpholine (NO donor) and thiomorpholine (NS donor) derivatives were synthesized and their thermal behavior and catalytic activity in epoxidation reaction of cis-diphenylethylene were studied using oxygen sources NaOCl. The
J I Levin et al.
Bioorganic & medicinal chemistry letters, 16(6), 1605-1609 (2006-01-24)
A series of thiomorpholine sulfonamide hydroxamate TACE inhibitors, all bearing propargylic ether P1' groups, was explored. In particular, compound 5h has excellent in vitro potency against isolated TACE enzyme and in cells, oral activity in a model of TNF-alpha production
B Combourieu et al.
Biodegradation, 9(6), 433-442 (1999-05-21)
Spectrophotometric assays of Mycobacterium aurum MO1 cells extracts gave evidence of a soluble cytochrome P450, involved in the degradative pathway of morpholine, a waste product from the chemical industry. In order to get further information, the kinetics of the biodegradation
Saurav Bera et al.
ACS combinatorial science, 14(1), 1-4 (2011-12-01)
Diastereoselective trans-2,5-disubstituted amino acids derived diverse morpholines, piperazines and thiomorpholines were prepared in 30 min-1 h with high yields through iodine-mediated 6-exotrig type cyclization from a single common synthetic intermediate. The displacement of iodine with hydride ion gave a methyl
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