196673
2′,3′,4′,5′,6′-五氟苯乙酮
97%
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线性分子式:
C6F5COCH3
化学文摘社编号:
分子量:
210.10
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
211-487-6
MDL number:
Assay:
97%
Form:
liquid
InChI key
FBGHCYZBCMDEOX-UHFFFAOYSA-N
InChI
1S/C8H3F5O/c1-2(14)3-4(9)6(11)8(13)7(12)5(3)10/h1H3
SMILES string
CC(=O)c1c(F)c(F)c(F)c(F)c1F
assay
97%
form
liquid
refractive index
n20/D 1.4366 (lit.)
bp
130-131 °C (lit.)
density
1.476 g/mL at 25 °C (lit.)
functional group
fluoro, ketone
Application
2′,3′,4′,5′,6′-五氟苯乙酮用于以聚球藻菌株 PCC 7942中分离的酮还原酶不对称合成手性醇。 它也用于合成苯扎五氟苯乙酮和2,3-二氢-F-苯扎苯乙酮。
General description
研究人员采用纳秒激光闪光光解技术研究了磁场对对Brij 35胶束溶液中2′,3′,4′,5′,6′-五氟苯乙酮光化学夺氢反应的影响。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
150.8 °F - closed cup
flash_point_c
66 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Polyfluoroaryl carbonyl chemistry. Benzalacetophenones.
Filler R, et al.
The Journal of Organic Chemistry, 40(7), 935-939 (1975)
Magnetic field effects on the photochemical hydrogen abstraction of 2′, 3′, 4′, 5′, 6′-pentafluoroacetophenone in a Brij 35 micellar solution.
Igarashi M, et al.
Molecular Physics, 82(6), 1165-1179 (1994)
Kathrin Hölsch et al.
Applied and environmental microbiology, 74(21), 6697-6702 (2008-09-16)
A new ketoreductase useful for asymmetric synthesis of chiral alcohols was identified in the cyanobacterium Synechococcus sp. strain PCC 7942. Mass spectrometry of trypsin-digested peptides identified the protein as 3-ketoacyl-[acyl-carrier-protein] reductase (KR) (EC 1.1.1.100). The gene, referred to as fabG
Francisco J Martínez-Navarro et al.
Developmental and comparative immunology, 108, 103666-103666 (2020-03-04)
Psoriasis is a skin inflammatory disorder that affects 3% of the human population. Although several therapies based on the neutralization of proinflammatory cytokines have been used with relative success, additional treatments are required. The in silico analysis of gene expression
Babak Razaghi et al.
Developmental dynamics : an official publication of the American Association of Anatomists, 247(2), 289-303 (2017-10-13)
In this study, we reveal a previously undescribed role of the HACE1 (HECT domain and Ankyrin repeat Containing E3 ubiquitin-protein ligase 1) tumor suppressor protein in normal vertebrate heart development using the zebrafish (Danio rerio) model. We examined the link
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