198048
三甲基铝 溶液
2.0 M in toluene
别名:
Trimethylalane
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关于此项目
线性分子式:
(CH3)3Al
化学文摘社编号:
分子量:
72.09
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587197
产品名称
三甲基铝 溶液, 2.0 M in toluene
InChI
1S/3CH3.Al/h3*1H3;
SMILES string
C[Al](C)C
InChI key
JLTRXTDYQLMHGR-UHFFFAOYSA-N
form
liquid
concentration
2.0 M in toluene
density
0.81 g/mL at 25 °C
Quality Level
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Application
三甲基铝溶液可用作合成以下物质的试剂：
- 通过不饱和糖苷的立体选择性重排生成多羟基化环己烷
- 用于烯烃聚合的部分水解三甲基铝（PHT）催化剂
- 采用镍-1,3-二环己基咪唑2-亚基催化体系通过苯甲醚衍生物的甲基化作用生成甲苯
用于最近报道的基于Oppenauer 反应的Al催化氧化，得到了高产量的醛和酮。 作为联萘酚的 (1:1) 络合物，以Novozym 435催化仲醇的动态动力学拆分。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1
target_organs
Central nervous system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
39.2 °F - closed cup
flash_point_c
4 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Nickel-catalyzed cross-coupling of anisole derivatives with trimethylaluminum through the cleavage of carbon-oxygen bonds
Morioka T, et al.
Chemistry Letters (Jpn), 44(12), 1729-1731 (2015)
Partially hydrolyzed trimethylaluminum (PHT) as heterogeneous cocatalyst for the polymerization of olefins with metallocene complexes
Koppl A, et al.
Journal of Applied Polymer Science, 80(3), 454-466 (2001)
Trimethylaluminium promoted rearrangements of unsaturated sugars into cyclohexanes
Jia C, et al.
Tetrahedron Asymmetry, 15(4), 699-703 (2004)
Lipase/aluminum-catalyzed dynamic kinetic resolution of secondary alcohols.
Albrecht Berkessel et al.
Angewandte Chemie (International ed. in English), 45(39), 6567-6570 (2006-09-05)
Christopher R Graves et al.
Journal of the American Chemical Society, 128(39), 12596-12597 (2006-09-28)
A highly active and selective Al-based catalytic Oppenauer (O) oxidation is reported. Quantitative and selective oxidations of a variety of benzylic, propargylic, allylic, and aliphatic primary and secondary alcohols were achieved using nitrobenzaldehyde derivatives as the oxidant and simple aluminum
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