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Merck
CN

204625

硫酸铊(I)

99.99% trace metals basis, solid

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关于此项目

线性分子式:
Tl2SO4
化学文摘社编号:
分子量:
504.83
UNSPSC Code:
12161600
eCl@ss:
38120904
PubChem Substance ID:
NACRES:
NA.22
EC Number:
231-201-3
MDL number:
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产品名称

硫酸铊(I), 99.99% trace metals basis

Quality Level

assay

99.99% trace metals basis

form

solid

reaction suitability

core: thallium, reagent type: catalyst

mp

632 °C (lit.)

density

6.77 g/mL at 25 °C (lit.)

SMILES string

[Tl+].[Tl+].[O-]S([O-])(=O)=O

InChI

1S/H2O4S.2Tl/c1-5(2,3)4;;/h(H2,1,2,3,4);;/q;2*+1/p-2

InChI key

YTQVHRVITVLIRD-UHFFFAOYSA-L

General description

Thallium(I) sulfate is mainly used in organic synthesis as an oxidizing agent. It can facilitate the oxidation of various organic compounds, such as alcohols, to corresponding aldehydes or ketones. This reaction is commonly known as the Reformatsky reaction.1 Additionally, thallium sulfate is employed in the preparation of thallium salts for use in analytical chemistry and research applications. It is also utilized in the production of luminous paints, photoelectric cells, and low-melting glasses.

Application

Thallium(I)sulfate is also utilized in:

  • the synthesis of alkylated cyclopentadienes and 7-substitutedbicyclo[2.2.1]heptane derivatives
  • inthe preparation of thallium borate species such as TlBPH43


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Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 2 - Skin Irrit. 2 - STOT RE 1 Oral

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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分析证书(COA)

Lot/Batch Number

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Methoxymethylation of thallous cyclopentadienide. Simplified preparation of a key intermediate for the synthesis of prostaglandins
Elias J. Corey, Urs Koelliker, and Jorg Neuffer
Journal of the American Chemical Society, 93(6), 1489?1490-1489?1490 (1971)
D B Peele et al.
Neurobehavioral toxicology and teratology, 8(3), 273-277 (1986-05-01)
Flavor aversions induced by intraperitoneal (IP) and oral (PO) administration of thallium sulfate were compared in a repeated trial, two-bottle preference test. Male Long-Evans rats (N = 6/group) were given 30-min access to a 0.1% saccharin solution followed 20-min later
Altered testicular enzyme patterns in rats after long-term exposure to thallium sulphate.
C Gregotti et al.
Journal de toxicologie clinique et experimentale, 5(4), 265-271 (1985-07-01)



全球贸易项目编号

货号GTIN
204625-5G04061838767127
204625-25G04061838767110