205338
四氯化碲
99%
别名:
Tellurium chloride, Tellurium(IV) chloride, Tetrachlorotellurium
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关于此项目
线性分子式:
TeCl4
化学文摘社编号:
分子量:
269.41
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
方案
99%
表单
powder, crystals or chunks
沸点
380 °C (lit.)
mp
224 °C (lit.)
密度
3.26 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Te](Cl)(Cl)Cl
InChI
1S/Cl4Te/c1-5(2,3)4
InChI key
SWLJJEFSPJCUBD-UHFFFAOYSA-N
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一般描述
基材原子序数：52 碲
应用
- 有机碲化合物的高效区域选择性合成：探索了四氯化碲与1-烯烃的反应，重点介绍了其在有机合成中的用途（VA Potapov et al., 2017）。
- 环化反应：TeCl4 可用作双亲电子环化（double-electrophilic cyclization）反应的双亲电子试剂，显示了其在有机转化中的多功能性 （N Korol, M Slivka, 2018）。
- 四氯化碲的区域和立体选择性加成：研究了甲基炔丙基醚中TeCl4 的加成，强调了加成过程的立体化学结构（MV Musalova et al., 2017）。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Maria V Musalova et al.
Molecules (Basel, Switzerland), 17(5), 5770-5779 (2012-05-17)
The reaction of tellurium tetrachloride with acetylene proceeds in a stereospecific anti-addition manner to afford the novel products E-2-chlorovinyltellurium trichloride and E,E-bis(2-chlorovinyl)tellurium dichloride. Reaction conditions for the selective preparation of each of these products were found. The latter was obtained
Shalini Roy et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 49(10), 2564-2574 (2011-07-12)
Tellurium tetrachloride (TeCl(4)) and diphenyl ditelluride (DPDT) cytotoxicity, was investigated in rat astrocytes. Concentrations of 0.24-250μM (24h) were tested for viability using MTT(3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyl tetrazolium bromide) and trypan blue exclusion. MTT showed significant decreases at all concentrations tested for both compounds.
P Mareeswari et al.
Enzyme and microbial technology, 95, 225-229 (2016-11-22)
We report an efficient method to biosynthesize biocompatible cadmium telluride and cadmium sulphide quantum dots from the fungus Rhizopus stolonifer. The suspension of the quantum dots exhibited purple and greenish-blue luminescence respectively upon UV light illumination. Photoluminescence spectroscopy, X-ray diffraction
Puneet Vij et al.
Environmental toxicology and pharmacology, 34(3), 768-782 (2012-10-17)
Diphenyl ditelluride (DPDT) and tellurium tetrachloride (TeCl(4)) were evaluated for toxicity in transformed (HT-29, Caco-2) and non-transformed colon cells (CCD-18Co). Significant decreases in viability were observed with DPDT exposure in HT-29 (62.5-1000 μM), Caco-2 (31.25-1000 μM) and CCD-18Co cells (500-1000
J F Van Vleet et al.
American journal of veterinary research, 43(11), 2000-2009 (1982-11-01)
Seventy newly hatched ducklings were fed a commercial ration with 500 mg of added Te (as tetrachloride)/kg of feed for up to 28 days. Ducklings were euthanatized at day 14, 21, and 28, the hearts were studied by gross, microscopic
商品
High Purity Metalorganic Precursors for CPV Device Fabrication
Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.
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