205354
(氯甲基)三甲基硅烷
98%
别名:
三甲基氯甲基硅烷
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关于此项目
线性分子式:
(CH3)3SiCH2Cl
化学文摘社编号:
分子量:
122.67
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-058-5
Beilstein/REAXYS Number:
906705
MDL number:
vapor pressure
~25 mmHg ( 20 °C)
Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.418 (lit.)
bp
98-99 °C (lit.)
density
0.879 g/mL at 25 °C (lit.)
functional group
chloro
SMILES string
C[Si](C)(C)CCl
InChI
1S/C4H11ClSi/c1-6(2,3)4-5/h4H2,1-3H3
InChI key
OOCUOKHIVGWCTJ-UHFFFAOYSA-N
Application
（氯甲基）三甲基硅烷可在三苯基膦存在下用醛或酮进行处理以合成末端烯烃。它也可被用于制备三甲基甲硅烷基甲基氯化镁，一种常用于Peterson亚甲基化的试剂。
Packaging
推荐将25毫升安全/密封™瓶作为一次性使用的瓶子。重复穿刺可能会导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
24.8 °F - closed cup
flash_point_c
-4 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
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Review SET mechanism in photoredox catalysis for sustainable reactions and rearrangement of oxaziridines.
Methylenation of Perfluoroalkyl Ketones using a Peterson Olefination Approach.
Hamlin T A, et al.
The Journal of Organic Chemistry, 79(3), 1145-1155 (2014)
Direct synthesis of terminal olefins from ketones. Application of (chloromethyl) trimethylsilane to a Wittig reaction.
Sekiguchi A and Ando W
The Journal of Organic Chemistry, 44(3), 413-415 (1979)
Synthesis of alkenes from carbonyl compounds and carbanions alpha to silicon. III. Full report and a synthesis of the sex pheromone of gypsy moth.
Chan T H and Chang E
The Journal of Organic Chemistry, 39(22), 3264-3268 (1974)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 205354-100ML | 04061838767653 |
| 205354-4X25ML | 04061838767660 |