205729
硫酸钡负载钯
extent of labeling: 5 wt. % loading, unreduced, powder
别名:
Rosenmund 催化剂, 钯/钡 4
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关于此项目
线性分子式:
Pd
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
硫酸钡负载钯, extent of labeling: 5 wt. % loading, unreduced
SMILES string
[Pd]
InChI
1S/Pd
InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
form
powder
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
extent of labeling
5 wt. % loading
greener alternative category
, Enabling
Quality Level
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Application
Palladium on barium sulfate (Pd/BaSO4), also known as Rosenmund catalyst, is used for the decarboxylation of aliphatic esters for further production of biodiesel. It can also be used in hydrogenation reaction. Pd/BaSO4 may be used as a catalyst reservoir for the Stille cross-coupling reaction between iodobenzene and tributylphenyltin.
Other Notes
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Palladium-catalyzed decarboxylation of higher aliphatic esters: Towards a new protocol to the second generation biodiesel production
Han J, et al.
Green Chemistry, 12(3), 463-467 (2010)
Palladium on carbon-catalyzed solvent-free and solid-phase hydrogenation and Suzuki-Miyaura reaction
Monguchi Y, et al.
Tetrahedron, 67(45), 8628-8634 (2011)
Stille cross-coupling reaction using Pd/BaSO4 as catalyst reservoir
Coelho AV, et al.
Applied Organometallic Chemistry, 22(1), 39-42 (2008)
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