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206555

4-碘甲苯

99%

别名:

4-碘代甲苯

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关于此项目

线性分子式:
CH3C6H4I
化学文摘社编号:
624-31-7
分子量:
218.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24852408
EC Number:
210-841-7
Beilstein/REAXYS Number:
1903637
MDL number:
MFCD00001059
Assay:
99%
Form:
solid
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Quality Level

100

assay

99%

form

solid

bp

211.5 °C (lit.)

mp

33-35 °C (lit.)

functional group

iodo

SMILES string

Cc1ccc(I)cc1

InChI

1S/C7H7I/c1-6-2-4-7(8)5-3-6/h2-5H,1H3

InChI key

UDHAWRUAECEBHC-UHFFFAOYSA-N

General description

4-碘甲苯在负载钯的 (Ni，Mg) 3 Si 2 O 5 (OH) 4 固溶体纳米管催化下与苯硼酸发生 Suzuki-Miyaura 偶联反应 。对钴催化 4-碘甲苯与硫酚和硫醇的偶联反应进行了研究 。研究了钯/铜催化的 4-碘甲苯与苯乙炔的薗头交叉偶联反应。

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302,H315

Hazard Classifications

Acute Tox. 4 Oral - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

194.0 °F - closed cup

flash_point_c

90 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCT8035
MKCP1685
MKCJ4215
MKCD9092
MKBV9477V

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Takashi Mino et al.
The Journal of organic chemistry, 71(25), 9499-9502 (2006-12-02)
Palladium/copper-catalyzed Sonogashira cross-coupling reaction of aryl halides with a variety of terminal alkynes under amine-free conditions in dimethylformamide (DMF) at 80 degrees C gave internal arylated alkynes using PdCl2(MeCN)2 with phosphine-free hydrazone 2a as a ligand and CuI as the
Wancheng Zhu et al.
Inorganic chemistry, 51(11), 6020-6031 (2012-05-16)
(Ni(1-x),Mg(x))(3)Si(2)O(5)(OH)(4) solid-solution nanotubes (NTs) with tunable compositions were hydrothermally synthesized by altering the molar ratio of Mg(2+) to Ni(2+). The as-synthesized NTs were loaded with sub-0.06 wt % palladium (Pd; ∼0.045 wt %) for Suzuki-Miyaura (SM) coupling reactions between iodobenzene
Ying-Chieh Wong et al.
Organic letters, 8(24), 5613-5616 (2006-11-17)
A new cobalt-catalyzed coupling of aryl halides with thiophenols and alkanethiols is reported. A variety of aryl sulfides can be prepared in excellent yields under mild reaction conditions using 1-2 mol % of CoI2(dppe) and Zn. This new cobalt-catalyzed coupling
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货号GTIN
206555-25G04061838768735
206555-100G04061838768728