208353
五氯化钼
95%
别名:
Molybdenum pentachloride, Pentachloromolybdenum
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关于此项目
线性分子式:
MoCl5
化学文摘社编号:
分子量:
273.21
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
95%
Form:
powder
Quality Level
vapor pressure
1.75 mmHg ( 25 °C), 131 mmHg ( 250 °C)
assay
95%
form
powder
reaction suitability
core: molybdenum, reagent type: catalyst
impurities
<0.5% insoluble matter
bp
268 °C (lit.)
mp
194 °C (lit.)
density
2.928 g/mL at 25 °C (lit.)
SMILES string
Cl[Mo](Cl)(Cl)(Cl)Cl
InChI
1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5
InChI key
GICWIDZXWJGTCI-UHFFFAOYSA-I
General description
氯化钼（V）是一种路易斯酸，被广泛用作许多有机反应的催化剂和试剂。它可以由钼金属的直接氯化或亚硫酰氯和 MoO3的加热回流制备。
Application
氯化钼（V）可用作以下反应的高效催化剂：
它也可用作合成氧化铝/钼纳米复合材料和亚甲基钼试剂的前体，用于化学选择性羰基烯化反应。
- 硝基苯和醇的缩合以及烯基锂试剂的C-C偶联。
- 苄基醇与磺胺和氨基甲酸酯的直接酰胺化反应。
它也可用作合成氧化铝/钼纳米复合材料和亚甲基钼试剂的前体，用于化学选择性羰基烯化反应。
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
Kumar, S. Manickam, M.
Chemical Communications (Cambridge, England), 1615-1615 (1997)
Kristina Hackeloer et al.
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
H I Ogawa et al.
Mutation research, 320(1-2), 133-140 (1994-01-01)
A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 208353-25G | 04061838769718 |
| 208353-100G | 04061838769701 |