208361
四氟硼酸银
98%
别名:
氟硼酸银
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关于此项目
线性分子式:
AgBF4
化学文摘社编号:
分子量:
194.67
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
98%
反应适用性
core: silver
reagent type: catalyst
mp
70-73 °C (lit.)
SMILES字符串
[Ag+].F[B-](F)(F)F
InChI
1S/Ag.BF4/c;2-1(3,4)5/q+1;-1
InChI key
CCAVYRRHZLAMDJ-UHFFFAOYSA-N
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一般描述
四氟硼酸银（AgBF4）在有机合成中被用作路易斯酸。它对有机卤化物有很高的亲和性。它可用于酰氯的活化、亲核取代、重排、环加成、环化、环扩张、氧化等有机反应。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Youhong Hu et al.
The Journal of organic chemistry, 67(7), 2365-2368 (2002-04-02)
We report here a general synthetic methodology for palladium-catalyzed carbonylative annulation of o-alkynylphenol to construct 2-substituted-3-aroyl-benzo[b]furan. On the basis of the results, this methodology could be applied to a wider selection of iodide substrates to generate desired products. In accordance
Synlett, 1901-1901 (2007)
Silver tetrafluoroborate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2005)
Silver tetrafluoroborate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2005)
Zbigniew J Kamiński et al.
Journal of the American Chemical Society, 127(48), 16912-16920 (2005-12-01)
A new generation of triazine-based coupling reagents (TBCRs), designed according to the concept of "superactive esters", was obtained by treatment of 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium (DMTMM) chloride with lithium or silver tetrafluoroborate. The structure of 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium tetrafluoroborate was confirmed by X-ray diffraction. Activation
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Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.
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