208450
氯化锗(IV)
99.99% trace metals basis
别名:
四氯化锗
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关于此项目
线性分子式:
GeCl4
化学文摘社编号:
分子量:
214.45
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-116-7
MDL number:
Assay:
99.99% trace metals basis
Form:
liquid
产品名称
氯化锗(IV), 99.99% trace metals basis
InChI key
IEXRMSFAVATTJX-UHFFFAOYSA-N
InChI
1S/Cl4Ge/c1-5(2,3)4
SMILES string
Cl[Ge](Cl)(Cl)Cl
vapor pressure
76 mmHg ( 20 °C)
assay
99.99% trace metals basis
form
liquid
reaction suitability
core: germanium
reagent type: catalyst
impurities
≤150.0 ppm Trace Metal Analysis
bp
83 °C (lit.)
mp
−49.5 °C (lit.)
density
1.844 g/mL at 25 °C
Quality Level
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Application
四氯化锗可用于微波制备 Ge 2 Cl 6 ，这是一种无色晶体材料，已被列入低价锗化合物的进一步研究中。GeCl 4 可用于锗硫属化合物薄膜的等离子体增强气相沉积。GeCl 4 与三苯基膦配合可用于还原编号 α-溴羧酸衍生物。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Does not sustain combustion.
flash_point_c
Does not sustain combustion.
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Triphenylphosphine/germanium(IV) chloride combination: A new agent for the reduction of a-bromo carboxylic acid derivatives
Kagoshima H, et al.
Tetrahedron Letters, 39(10), 1203-1206 (1998)
GeS2 and GeSe2 PECVD from GeCl4 and Various Chalcogenide Precursors.
Whitham PJ, et al.
Plasma Chemistry and Plasma Processing, 34(4), 755-766 (2014)
Zheng Gong et al.
Physical chemistry chemical physics : PCCP, 19(36), 24513-24521 (2017-07-20)
Spinel-phase Zn
Ian R. Beattie et al.
Inorganic chemistry, 37(23), 6032-6034 (2001-10-24)
The Raman spectrum of Ge(2)Cl(6) shows close analogies with that of the isoelectronic [Ga(2)Cl(6)](2)(-). A band at 262 cm(-)(1) is assigned as principally a Ge-Ge stretching mode. The compound is very moisture-sensitive and decomposes readily in vacuo to give GeCl(4)
Zehui Zhang et al.
ChemSusChem, 4(1), 131-138 (2011-01-13)
Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly process. Monosaccharides D-fructose and D-glucose, disaccharides sucrose and maltose, and even the polysaccharide cellulose were
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