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Merck
CN

208523

三氯化钌

solid, Ru content 45-55%

别名:

Ruthenium trichloride

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关于此项目

线性分子式:
RuCl3
化学文摘社编号:
10049-08-8
分子量:
207.43
NACRES:
NA.22
PubChem Substance ID:
24852520
UNSPSC Code:
12161600
EC Number:
233-167-5
MDL number:
MFCD00011208

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产品名称

三氯化钌, Ru content 45-55%

InChI key

YBCAZPLXEGKKFM-UHFFFAOYSA-K

InChI

1S/3ClH.Ru/h3*1H;/q;;;+3/p-3

SMILES string

Cl[Ru](Cl)Cl

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

density

3.11 g/mL at 25 °C (lit.)

Quality Level

200

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相关类别

Application

氯化钌（III）可用作以下反应的催化剂：：

  • 通过环氧化物与苯胺的亲核开环反应合成β‐氨基醇。
  • 在温和条件下各种酚、醇、硫醇和胺的乙酰化反应。
  • 通过混合醛、胺和三甲基氰硅烷合成α‐氨基腈。

General description

氯化钌（III）是一种化合物，它可用作温和的路易斯酸催化剂，用于醛的缩醛化、醇的缩醛化和酮肟向酰胺的转化。 此外，它也可作为前体用于合成钌纳米颗粒。

Other Notes

不溶物形式

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000444209
0000444209
MKCW7012
MKCV8944
MKCV8943

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RuCl3 Catalyzed One-Pot Synthesis of ?-Aminonitriles
De SK
Synthetic Communications, 35(5), 653-656 (2005)
Ruthenium (III) chloride-catalyzed ring opening of epoxides with aromatic amines
De SK and Gibbs RA
Synthetic Communications, 35(20), 2675-2680 (2005)
Halloysite nanotube supported Ru nanocatalysts synthesized by the inclusion of preformed Ru nanoparticles for preferential oxidation of CO in H2-rich atmosphere
Wang L, et al
The Journal of Physical Chemistry C, 117(8), 4141-4151 (2013)
Takaya Terashima et al.
Macromolecular rapid communications, 33(9), 833-841 (2012-04-25)
Multifunctional microgel-core star polymers with ruthenium catalysts are designed as catalyst-bearing nanoreactors to improve activity, controllability, and functionality tolerance in living radical polymerization. Multifunctional ligands are efficiently incorporated into the core of star polymers by sequential tandem procedures: 1) ruthenium-catalyzed
Wanqing Teng et al.
Frontiers in chemistry, 8, 334-334 (2020-05-21)
It is highly promising to design and develop efficient and economical electrocatalysts for oxygen evolution reaction (OER) in alkaline solution. In this work, we prepare FeCoNi sulfide composites (including FeS, Co3S4, and Ni3S4) derived from in situ sulfurization of precursor
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