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Merck
CN

208523

Sigma-Aldrich

三氯化钌

solid, Ru content 45-55%

别名:

Ruthenium trichloride

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关于此项目

线性分子式:
RuCl3
化学文摘社编号:
10049-08-8
分子量:
207.43
EC 号:
233-167-5
MDL编号:
MFCD00011208
UNSPSC代码:
12161600
PubChem化学物质编号:
24852520
NACRES:
NA.22

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产品名称

三氯化钌, Ru content 45-55%

质量水平

200

表单

solid

反应适用性

core: ruthenium
reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

密度

3.11 g/mL at 25 °C (lit.)

SMILES字符串

Cl[Ru](Cl)Cl

InChI

1S/3ClH.Ru/h3*1H;/q;;;+3/p-3

InChI key

YBCAZPLXEGKKFM-UHFFFAOYSA-K

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相关类别

一般描述

氯化钌（III）是一种化合物，它可用作温和的路易斯酸催化剂，用于醛的缩醛化、醇的缩醛化和酮肟向酰胺的转化。 此外，它也可作为前体用于合成钌纳米颗粒。

应用

氯化钌（III）可用作以下反应的催化剂：：

  • 通过环氧化物与苯胺的亲核开环反应合成β‐氨基醇。
  • 在温和条件下各种酚、醇、硫醇和胺的乙酰化反应。
  • 通过混合醛、胺和三甲基氰硅烷合成α‐氨基腈。

其他说明

不溶物形式

警示用语：

Danger

危险声明

H302,H314,H411

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000444209
0000444209
MKCW7012
MKCV8944
MKCV8943

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Sébastien Perdriau et al.
ChemSusChem, 5(12), 2427-2434 (2012-10-13)
Cardanol, a constituent of cashew nutshell liquid (CNSL), was subjected to transfer hydrogenation catalyzed by RuCl(3) using isopropanol as a reductant. The side chain of cardanol, which is a mixture of a triene, a diene, and a monoene, was selectively
Ruthenium (III) chloride-catalyzed ring opening of epoxides with aromatic amines
De SK and Gibbs RA
Synthetic Communications, 35(20), 2675-2680 (2005)
Hitoshi Harada et al.
The Journal of organic chemistry, 73(17), 6772-6779 (2008-08-07)
Highly enantioselective catalytic intramolecular ortho-alkylation of aromatic imines containing alkenyl groups tethered at the meta position relative to the imine directing group has been achieved using [RhCl(coe)2]2 and chiral phosphoramidite ligands. Cyclization of substrates containing 1,1- and 1,2-disubstituted as well
Halloysite nanotube supported Ru nanocatalysts synthesized by the inclusion of preformed Ru nanoparticles for preferential oxidation of CO in H2-rich atmosphere
Wang L, et al
The Journal of Physical Chemistry C, 117(8), 4141-4151 (2013)
Shū Kobayashi et al.
Organic letters, 4(8), 1319-1322 (2002-04-13)
Several transition metal salts were found to catalyze aza-Michael reactions of enones with carbamates efficiently. The catalytic activity was strongly dependent on the nature of the metal salts. While conventional Lewis acids such as BF(3).OEt(2), AlCl(3), or TiCl(4) showed lower
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