208981
六氯铱(IV)酸钾
technical grade
别名:
Iridium potassium chloride
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关于此项目
线性分子式:
K2IrCl6
化学文摘社编号:
分子量:
483.13
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
等级
technical grade
表单
powder
反应适用性
core: potassium
浓度
≥39.0% Ir (gravimetric)
mp
>385 °C (lit.)
SMILES字符串
[K+].[K+].Cl[Ir--](Cl)(Cl)(Cl)(Cl)Cl
InChI
1S/6ClH.Ir.2K/h6*1H;;;/q;;;;;;+4;2*+1/p-6
InChI key
WEKZJZDULNNSCD-UHFFFAOYSA-H
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警示用语:
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
V Duarte et al.
Nucleic acids research, 27(2), 496-502 (1998-12-24)
Oxidative damage to DNA bases commonly resultsin the formation of oxidized purines, particularly 7,8-dihydro-8-oxoguanine (8-oxoG) and 7,8-dihydro-8-oxoadenine (8-oxoA), the former being a well-known mutagenic lesion. Since 8-oxoG is readily subject to further oxidation compared with normal bases, the insertion of
G M Kolodny et al.
Cancer research, 43(7), 3101-3103 (1983-07-01)
Sodium hexachloroiridate injected 1 day after i.p. injection of 10(6) mouse ovarian tumor cells prevents the appearance of ascitic tumors in mice. Mice given injections of tumor cells all die at 20 to 30 days after tumor injection. Mice treated
Nootan Bhattarai et al.
Inorganic chemistry, 51(24), 13303-13311 (2012-11-29)
The aqueous oxidations of glutathione (GSH) by [IrCl(6)](2-), [Fe(bpy)(2)(CN)(2)](+), and [Fe(bpy)(CN)(4)](-) are described. All three reactions are highly susceptible to catalysis by traces of copper ions, but this catalysis can be fully suppressed with suitable chelating agents. The direct oxidation
Salah Boussaad et al.
Journal of the American Chemical Society, 130(12), 3780-3787 (2008-03-07)
In an effort to develop sensitive nanoscale devices for chemical and biological sensing, we have examined, using liquid gating, the conductance of semiconducting single-walled carbon nanotube-based field-effect transistors (SWCNT-FETs) in the presence of redox mediators. As examples, redox couples K3Fe(CN)6/K4Fe(CN)6
J G Muller et al.
Nucleic acids research, 26(9), 2247-2249 (1998-06-20)
Two gel electrophoretic methods are described for detection of 7, 8-dihydro-8-oxoguanine and 7,8-dihydro-8-oxoadenine based on their further oxidation with one-electron oxidants including IrCl62-and IrBr62-. The products of nucleobase oxidation lead to enhanced piperidine-sensitive cleavage and to highly visible stop points
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