209686
铱
powder, 99.9% trace metals basis
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关于此项目
经验公式（希尔记法）:
Ir
化学文摘社编号:
分子量:
192.22
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141720
EC Number:
231-095-9
MDL number:
产品名称
铱, powder, 99.9% trace metals basis
InChI key
GKOZUEZYRPOHIO-UHFFFAOYSA-N
InChI
1S/Ir
SMILES string
[Ir]
assay
99.9% trace metals basis
form
powder
resistivity
4.71 μΩ-cm
bp
4130 °C (lit.)
mp
2450 °C (lit.)
density
22.65 g/cm3 (lit.)
Quality Level
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Application
- 用于酸性介质中高效水氧化的铱基双钙钛矿：该研究强调了基于铱的双钙钛矿的开发，该物质可以在降低铱含量的同时保持水氧化的高活性和稳定性，对于材料科学中与能源相关的应用具有重要意义（Diaz-Morales et al., 2016）。
- 氧化铱析氧反应机理的研究进展：本文分析了氧化铱析氧反应（OER）机制，这对于改善工业应用中的催化过程至关重要（Naito et al., 2021）。
- 氧化铱的制备及应用：回顾：一篇全面的综述，讨论铱氧化物的各种制造方法及其应用，特别是与药物发现和材料科学相关的传感器和催化剂方面（Chen et al., 2020）。
General description
铱是稀有的高密度过渡金属，铂族金属成员之一。以其优越的理化性质著称。铱可用于高温应用，例如晶体生长坩埚，因其高熔点和高温稳定性可用于制造在极端条件下工作的仪器。优异的耐腐蚀性和导电性可用于制造电触头和电极。此外，铱还可作为催化剂用于各种有机反应，包括加氢反应、水分解反应、C-C偶联反应和烯烃复分解反应。
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1
存储类别
4.1B - Flammable solid hazardous materials
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Dik-Lung Ma et al.
PloS one, 8(2), e55751-e55751 (2013-03-05)
A cell permeable cyclometalated iridium(III) complex has been developed as a phosphorescent probe for cell imaging. The iridium(III) solvato complex [Ir(phq)2(H2O]2)] preferentially stains the cytoplasm of both live and dead cells with a bright luminescence.
Hana Woo et al.
Journal of the American Chemical Society, 135(12), 4771-4787 (2013-03-06)
Despite the promising photofunctionalities, phosphorescent probes have been examined only to a limited extent, and the molecular features that provide convenient handles for controlling the phosphorescence response have yet to be identified. We synthesized a series of phosphorescence zinc sensors
Matthew R Kelley et al.
Inorganic chemistry, 52(5), 2564-2580 (2013-02-21)
A series of seven [Ir{ArNC(NR2)NAr}(cod)] complexes (1a-1g; where R = Me or Et; Ar = Ph, 4-MeC6H4, 4-MeOC6H4, 2,6-Me2C6H3, or 2,6-(i)Pr2C6H3; and cod = 1,5-cyclooctadiene) were synthesized by two different methods from the neutral guanidines, ArN═C(NR2)NHAr, using either MeLi and
Rui Cao et al.
Journal of medicinal chemistry, 56(9), 3636-3644 (2013-04-19)
The cellular behavior and toxicity effect of organometallic complexes depend largely on their peripheral ligands. In this study, we have synthesized a series of novel luminescent cationic iridium(III) complexes by tuning the ancillary N(∧)N ligand based on a structure [Ir(ppy)2(N(∧)N)](+)
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played
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