assay
99.9% trace metals basis
form
powder
reaction suitability
core: iridium
resistivity
4.71 μΩ-cm
bp
4130 °C (lit.)
mp
2450 °C (lit.)
density
22.65 g/cm3 (lit.)
SMILES string
[Ir]
InChI
1S/Ir
InChI key
GKOZUEZYRPOHIO-UHFFFAOYSA-N
General description
铱是稀有的高密度过渡金属，铂族金属成员之一。以其优越的理化性质著称。铱可用于高温应用，例如晶体生长坩埚，因其高熔点和高温稳定性可用于制造在极端条件下工作的仪器。优异的耐腐蚀性和导电性可用于制造电触头和电极。此外，铱还可作为催化剂用于各种有机反应，包括加氢反应、水分解反应、C-C偶联反应和烯烃复分解反应。
Application
- 用于酸性介质中高效水氧化的铱基双钙钛矿：该研究强调了基于铱的双钙钛矿的开发，该物质可以在降低铱含量的同时保持水氧化的高活性和稳定性，对于材料科学中与能源相关的应用具有重要意义（Diaz-Morales et al., 2016）。
- 氧化铱析氧反应机理的研究进展：本文分析了氧化铱析氧反应（OER）机制，这对于改善工业应用中的催化过程至关重要（Naito et al., 2021）。
- 氧化铱的制备及应用：回顾：一篇全面的综述，讨论铱氧化物的各种制造方法及其应用，特别是与药物发现和材料科学相关的传感器和催化剂方面（Chen et al., 2020）。
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signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1
存储类别
4.1B - Flammable solid hazardous materials
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols
José Luis Núñez-Rico et al.
Organic letters, 15(8), 2066-2069 (2013-04-12)
Iridium(I) complexes of enantiomerically pure phosphine-phosphite ligands ([Ir(Cl)(cod)(P-OP)]) efficiently catalyze the enantioselective hydrogenation of diverse C═N-containing heterocyclic compounds (benzoxazines, benzoxazinones, benzothiazinones, and quinoxalinones; 25 examples, up to 99% ee). A substrate-to-catalyst ratio as high as 2000:1 was reached.
Rui Cao et al.
Journal of medicinal chemistry, 56(9), 3636-3644 (2013-04-19)
The cellular behavior and toxicity effect of organometallic complexes depend largely on their peripheral ligands. In this study, we have synthesized a series of novel luminescent cationic iridium(III) complexes by tuning the ancillary N(∧)N ligand based on a structure [Ir(ppy)2(N(∧)N)](+)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 209686-500MG | 04061838770899 |