质量水平
方案
99.9% trace metals basis
表单
powder
电阻率
4.71 μΩ-cm
沸点
4130 °C (lit.)
mp
2450 °C (lit.)
密度
22.65 g/cm3 (lit.)
SMILES字符串
[Ir]
InChI
1S/Ir
InChI key
GKOZUEZYRPOHIO-UHFFFAOYSA-N
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一般描述
铱是稀有的高密度过渡金属，铂族金属成员之一。以其优越的理化性质著称。铱可用于高温应用，例如晶体生长坩埚，因其高熔点和高温稳定性可用于制造在极端条件下工作的仪器。优异的耐腐蚀性和导电性可用于制造电触头和电极。此外，铱还可作为催化剂用于各种有机反应，包括加氢反应、水分解反应、C-C偶联反应和烯烃复分解反应。
应用
- 用于酸性介质中高效水氧化的铱基双钙钛矿：该研究强调了基于铱的双钙钛矿的开发，该物质可以在降低铱含量的同时保持水氧化的高活性和稳定性，对于材料科学中与能源相关的应用具有重要意义（Diaz-Morales et al., 2016）。
- 氧化铱析氧反应机理的研究进展：本文分析了氧化铱析氧反应（OER）机制，这对于改善工业应用中的催化过程至关重要（Naito et al., 2021）。
- 氧化铱的制备及应用：回顾：一篇全面的综述，讨论铱氧化物的各种制造方法及其应用，特别是与药物发现和材料科学相关的传感器和催化剂方面（Chen et al., 2020）。
警示用语：
Danger
危险声明
危险分类
Flam. Sol. 1
储存分类代码
4.1B - Flammable solid hazardous materials
WGK
nwg
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Chun-I Lee et al.
Journal of the American Chemical Society, 135(9), 3560-3566 (2013-02-05)
Compounds with carbon-boron bonds are versatile intermediates for building more complex molecules via the elaboration of the carbon-boron bonds into other carbon-element bonds. The synthesis of carbon-boron bonds by catalytic dehydrogenative borylation of carbon-hydrogen bonds with dialkoxyboranes (RO)2BH is particularly
Daniel Shiu-Hin Chan et al.
PloS one, 8(3), e60114-e60114 (2013-03-28)
We report herein a novel luminescent iridium(III) complex with two hydrophobic carbon chains as a non-reaction based chemosensor for the detection of Hg(2+) ions in aqueous solution (<0.002% of organic solvent attributed to the probe solution). Upon the addition of
Rui Cao et al.
Journal of medicinal chemistry, 56(9), 3636-3644 (2013-04-19)
The cellular behavior and toxicity effect of organometallic complexes depend largely on their peripheral ligands. In this study, we have synthesized a series of novel luminescent cationic iridium(III) complexes by tuning the ancillary N(∧)N ligand based on a structure [Ir(ppy)2(N(∧)N)](+)
Yuyang Zhou et al.
Chemical communications (Cambridge, England), 49(31), 3230-3232 (2013-03-14)
Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as living cell imaging reagents and
José Luis Núñez-Rico et al.
Organic letters, 15(8), 2066-2069 (2013-04-12)
Iridium(I) complexes of enantiomerically pure phosphine-phosphite ligands ([Ir(Cl)(cod)(P-OP)]) efficiently catalyze the enantioselective hydrogenation of diverse C═N-containing heterocyclic compounds (benzoxazines, benzoxazinones, benzothiazinones, and quinoxalinones; 25 examples, up to 99% ee). A substrate-to-catalyst ratio as high as 2000:1 was reached.
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