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210145

2,2-二甲基-1,3-二噁烷-4,6-二酮

Name: 2,2-二甲基-1,3-二噁烷-4,6-二酮
Brand: ALDRICH

98%

别名:

丙二酸亚异丙酯, 丙二酸环亚异丙酯, 米氏酸

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关于此项目

经验公式（希尔记法）:

C₆H₈O₄

化学文摘社编号:

2033-24-1

分子量:

144.13

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24852618

EC Number:

217-992-8

Beilstein/REAXYS Number:

117310

MDL number:

MFCD00006638

Assay:

98%

Form:

solid

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属性

Quality Level

200

assay

98%

form

solid

mp

92-96 °C (lit.)

solubility

dioxane: soluble 5%, clear to very slightly hazy, colorless to faintly yellow

functional group

ester, ketal

storage temp.

2-8°C

SMILES string

CC1(C)OC(=O)CC(=O)O1

InChI

1S/C6H8O4/c1-6(2)9-4(7)3-5(8)10-6/h3H2,1-2H3

InChI key

GXHFUVWIGNLZSC-UHFFFAOYSA-N

说明

General description

2,2-二甲基-1,3-二恶烷-4,6-二酮（米氏′酸）广泛用于有机合成，特别是对于多种CC键形成，因为它具有足够的酸性 (pK_a 4.83) 和空间刚性。醛与米氏′酸之间的Knoevenagel缩合反应在离子液体中加速。

米氏′酸被用作合成杂环的有价值的起始原料和有机合成反应的中间体。

Application

2,2-二甲基-1,3-二恶烷-4,6-二酮用于合成：

大环 β-酮内酯
4-吡啶基取代的杂环
2-取代吲哚
异秦皮啶。

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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货号	GTIN
210145-10G	04061838771155
210145-25G	04061838771162
210145-100G	04061838771148