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Merck
CN

21039

碳化钙

granulated, technical, ≥75% (gas-volumetric)

别名:

Calcium acetylide, Calcium dicarbide

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关于此项目

线性分子式:
CaC2
化学文摘社编号:
分子量:
64.10
UNSPSC Code:
12352300
NACRES:
NA.23
PubChem Substance ID:
EC Number:
200-848-3
Beilstein/REAXYS Number:
3909011
MDL number:
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grade

technical

Quality Level

assay

≥75% (gas-volumetric)

form

pieces

quality

granulated

reaction suitability

core: calcium

particle size

0.1-1 mm

density

2.22 g/mL at 25 °C (lit.)

SMILES string

[Ca++].[C-]#[C-]

InChI

1S/C2.Ca/c1-2;/q-2;+2

InChI key

UIXRSLJINYRGFQ-UHFFFAOYSA-N

General description

碳化钙(CaC2),又称乙炔钙,是一种离子化合物。技术级CaC2 是一种呈灰色的颗粒状固体。遇水反应形成乙炔气体和氢氧化钙。本品为技术级,含≥75% CaC2,其它成分为氧化钙、磷化物、硫化物和氮化物。CaC2广泛用于生产乙炔和氰氨化钙。此外,它还用于制造相变材料,并作为可高效利用太阳能的定形相变材料。还用作可充电钙电池的电池材料。

Application

  • NUCLEOPHILIC ADDITION OF PHOSPHINOXIDES AND ALCOHOLS TO ACETYLENE GENERATED in situ FROM CALCIUM CARBIDE:研究讨论碳化钙生成的乙炔用于各种有机合成的反应活性(Aleksandrovna, 2024)。
  • Construction of 3-Methyl-2-Substituted Benzofurans and 3-Methyl-2-Substituted Benzothiophenes Using Solid Calcium Carbide as a Substitute for Gaseous …:描述一种使用固体碳化钙的有机合成方法,说明它的实用性和环境意义(Wang et al., 2024)。


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signalword

Danger

target_organs

Respiratory system

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react. 1

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Mirian Elizabeth Casco et al.
Nanoscale, 11(11), 4712-4718 (2019-03-07)
We report the one-pot mechanochemical synthesis of N-doped porous carbons at room temperature using a planetary ball mill. The fast reaction (5 minutes) between calcium carbide and cyanuric chloride proceeds in absence of any solvent and displays a facile bottom-up
Yingjie Li et al.
Journal of environmental sciences (China), 68, 169-176 (2018-06-18)
For the first time, a series of alkynyl carbon materials (ACMs) were prepared via the mechanochemical reaction of CaC2 with six polyhalogenated precursors, namely CCl4, C2Cl6, C2Cl4, C6Cl6, C6Br6, and C14H4Br10 (ACM-1, ACM-2, ACM-3, ACM-4, ACM-5, and ACM-6, respectively) and
H Kjuus et al.
British journal of industrial medicine, 43(4), 237-242 (1986-04-01)
The overall mortality and the incidence of cancer have been studied among male employees at a plant producing calcium carbide. The cohort was defined as all men employed at the plant for at least 18 months in the period 1953



全球贸易项目编号

货号GTIN
21039-1KG-F04061838771254
21039-100G-F04061838771247