21039
碳化钙
granulated, technical, ≥75% (gas-volumetric)
别名:
Calcium acetylide, Calcium dicarbide
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关于此项目
线性分子式:
CaC2
化学文摘社编号:
分子量:
64.10
UNSPSC Code:
12352300
NACRES:
NA.23
PubChem Substance ID:
EC Number:
200-848-3
Beilstein/REAXYS Number:
3909011
MDL number:
InChI key
UIXRSLJINYRGFQ-UHFFFAOYSA-N
InChI
1S/C2.Ca/c1-2;/q-2;+2
SMILES string
[Ca++].[C-]#[C-]
grade
technical
assay
≥75% (gas-volumetric)
form
pieces
quality
granulated
particle size
0.1-1 mm
density
2.22 g/mL at 25 °C (lit.)
Quality Level
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General description
碳化钙(CaC2)，又称乙炔钙，是一种离子化合物。技术级CaC2 是一种呈灰色的颗粒状固体。遇水反应形成乙炔气体和氢氧化钙。本品为技术级，含≥75% CaC2，其它成分为氧化钙、磷化物、硫化物和氮化物。CaC2广泛用于生产乙炔和氰氨化钙。此外，它还用于制造相变材料，并作为可高效利用太阳能的定形相变材料。还用作可充电钙电池的电池材料。
Application
- NUCLEOPHILIC ADDITION OF PHOSPHINOXIDES AND ALCOHOLS TO ACETYLENE GENERATED in situ FROM CALCIUM CARBIDE：研究讨论碳化钙生成的乙炔用于各种有机合成的反应活性(Aleksandrovna, 2024)。
- Construction of 3-Methyl-2-Substituted Benzofurans and 3-Methyl-2-Substituted Benzothiophenes Using Solid Calcium Carbide as a Substitute for Gaseous …：描述一种使用固体碳化钙的有机合成方法，说明它的实用性和环境意义(Wang et al., 2024)。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 1
target_organs
Respiratory system
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
监管及禁止进口产品
此项目有
Mirian Elizabeth Casco et al.
Nanoscale, 11(11), 4712-4718 (2019-03-07)
We report the one-pot mechanochemical synthesis of N-doped porous carbons at room temperature using a planetary ball mill. The fast reaction (5 minutes) between calcium carbide and cyanuric chloride proceeds in absence of any solvent and displays a facile bottom-up
Yingjie Li et al.
Journal of environmental sciences (China), 68, 169-176 (2018-06-18)
For the first time, a series of alkynyl carbon materials (ACMs) were prepared via the mechanochemical reaction of CaC2 with six polyhalogenated precursors, namely CCl4, C2Cl6, C2Cl4, C6Cl6, C6Br6, and C14H4Br10 (ACM-1, ACM-2, ACM-3, ACM-4, ACM-5, and ACM-6, respectively) and
Production of calcium carbide from fine biochars.
Guodong Li et al.
Angewandte Chemie (International ed. in English), 49(45), 8480-8483 (2010-09-14)
G Malla et al.
Chemosphere, 58(2), 141-147 (2004-12-02)
Mitigation of methane (CH4) and nitrous oxide (N2O) emissions from soil is important to reduce the global warming. Efficacy of five nitrification inhibitors, i.e. neem (Azadirachta melia) cake, thiosulphate, coated calcium carbide, neem oil coated urea and dicyandiamide (DCD) and
Xiaoguang Jiao et al.
Science in China. Series C, Life sciences, 48 Suppl 1, 26-32 (2005-08-11)
A field experiment was carried out at the Shenyang Experimental Station of Ecology (CAS) in order to study the effects of slow-release urea fertilizers high polymer-coated urea (SRU1), SRU1 mixed with dicyandiamide DCD (SRU2), and SRU1 mixed with calcium carbide
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