跳转至内容
Merck
CN

212776

氢化铝锂 溶液

1.0 M in THF

别名:

LAH, 丙氨酸锂, 四氢铝酸锂

登录 查看组织和合同定价。

选择尺寸

关于此项目

线性分子式:
LiAlH4
化学文摘社编号:
16853-85-3
分子量:
37.95
NACRES:
NA.22
PubChem Substance ID:
24852740
UNSPSC Code:
26111700
MDL number:
MFCD00011075

主要文件

查看所有文档
技术服务
需要帮助？我们经验丰富的科学家团队随时乐意为您服务。
让我们为您提供帮助
技术服务
需要帮助？我们经验丰富的科学家团队随时乐意为您服务。
让我们为您提供帮助

产品名称

氢化铝锂 溶液, 1.0 M in THF

InChI

1S/Al.Li.4H/q-1;+1;;;;

SMILES string

[Li+].[AlH4-]

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

form

liquid

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

density

0.905 g/mL at 25 °C

storage temp.

2-30°C

Quality Level

200

正在寻找类似产品? 访问 产品对比指南

相关类别

Application

反应物或试剂用于：
  • 由油酸制备热塑性聚酯聚酰胺
  • 锂聚合物电池
  • 宝石-二氟亚甲基衍生物的加氢脱氟
  • 不对称羟醛反应
  • 具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成

LAH 是许多不同还原反应的强还原剂，例如酮类与醇类的还原反应

Packaging

建议将 25 mL Sure/Seal™ 瓶作为一次性瓶使用。 反复穿刺可能会导致产品性能下降。
查看可回收的容器产品。

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

法规信息

监管及禁止进口产品
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBT1133
SHBS6586
SHBQ7473
SHBN8878
SHBN5963

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. Why is Product 212776, Lithium aluminum hydride solution, considered carcinogenic?

    The carcinogen reference comes from Tetrahydrofuran (THF).  The solution is 90% THF.  The THF reference is form the National Toxicology Program (NTP) database.

  4. Product 212776, Lithium aluminum hydride solution, appears to container a precipitate in it.  Is it still OK to use?

    Most if not all solid lithium aluminum hydride will contain some form of insoluble oxides from slight air exposure.  You should be able to filter the insolubles - keeping air exposure to a minimum is the key. This procedure should be done entirely under argon (argon is typically a drier gas than nitrogen). If the final solution is exposed to air at any time, insolubles will be formed which will  then require further filtration to get clear again.

  5. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  6. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  7. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Damián E Bikiel et al.
Inorganic chemistry, 44(15), 5286-5292 (2005-07-19)
The nature of the solute species present in ethereal solutions of LiAlH(4) is of crucial importance for understanding the mechanisms for the reduction of ketones and other functional groups by LiAlH(4). We have employed a combination of theoretical and experimental
Byung-Hoon Jeong et al.
Journal of neuropathology and experimental neurology, 68(8), 870-879 (2009-07-17)
Previous studies indicate that RNA may be required for proteinase-resistant prion protein (PrP) amplification and for infectious prion formation in vitro, suggesting that RNA molecules may function as cellular cofactors for abnormal PrP (PrPSc) formation and become part of the
Krishnananda Samanta et al.
Bioorganic & medicinal chemistry letters, 20(1), 283-287 (2009-11-26)
A series of new benzoxazepine derivatives substituted with different alkoxy and aryloxy group were synthesized comprising synthetic steps of Mitsunobu reaction, lithium aluminum hydride (LAH) reduction, followed by debenzylation and finally intramolecular Mitsunobu cyclization. The new benzoxazepines specifically inhibited growth
Diastereoselective reductive amination of aryl trifluoromethyl ketones and alpha-amino esters.
Greg Hughes et al.
Angewandte Chemie (International ed. in English), 46(11), 1839-1842 (2007-04-24)
Andreas Grubelnik et al.
Journal of separation science, 31(10), 1739-1744 (2008-05-08)
Bacterial poly(hydroxyalkanoates) (PHAs) vary in the composition of their monomeric units. Besides saturated side-chains, unsaturated ones can also be found. The latter leads to unwanted by-products (THF ester, secondary alcohols) during acidic cleavage of the polymer backbone in the conventional
查看所有相关文献

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系客户支持