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Merck
CN

212792

氢化铝锂 溶液

1.0 M in diethyl ether

别名:

LAH, 丙氨酸锂, 四氢铝酸锂

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关于此项目

线性分子式:
LiAlH4
化学文摘社编号:
分子量:
37.95
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
Form:
liquid
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InChI

1S/Al.Li.4H/q-1;+1;;;;

SMILES string

[Li+].[AlH4-]

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

form

liquid

reaction suitability

reagent type: reductant

concentration

1.0 M in diethyl ether

density

0.716 g/mL at 25 °C

storage temp.

2-30°C

Quality Level

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Application

反应物或试剂用于:
  • 由油酸制备热塑性聚酯聚酰胺
  • 锂聚合物电池
  • 宝石-二氟亚甲基衍生物的加氢脱氟
  • 不对称羟醛反应
  • 具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成

LAH 是许多不同还原反应的强还原剂,例如酮类与醇类的还原反应

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 1

target_organs

Central nervous system

supp_hazards

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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José M Concellón et al.
The Journal of organic chemistry, 71(17), 6420-6426 (2006-08-12)
The reaction of chiral (2R,1'S)- or (2S,1'S)-2-(1-aminoalkyl)epoxides, 1 or 2 with a variety of organolithium compounds to obtain the corresponding (alphaS,betaS)- or (alphaR,betaS)- beta-amino alcohols in enantiopure form is reported. In both cases, the opening of the oxirane ring at
Hao Yao et al.
Journal of electron microscopy, 60(6), 375-378 (2011-10-05)
A plastic bag method was developed to observe air-sensitive samples on microstructure and phase distribution without exposure to air during the holder transfer process into the transmission electron microscope (TEM). As an example, a type of lithium aluminum hydride (Li(3)AlH(6))
I-Chi Lee et al.
Organic & biomolecular chemistry, 9(22), 7655-7658 (2011-09-17)
Specific deuterated reference compounds were prepared to probe the stereoselectivity of the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD(3) revealed a retentive stereoselectivity probably through the rare S(N)i (internal nucleophilic substitution) mechanism. An S(N)1-like mechanism occurs in the acid-promoted
Masateru Nishihara et al.
Archaea (Vancouver, B.C.), 1(2), 123-131 (2005-04-05)
A choline-containing phospholipid (PL-4) in Methanopyrus kandleri cells was identified as archaetidylcholine, which has been described by Sprott et al. (1997). The PL-4 consisted of a variety of molecular species differing in hydrocarbon composition. Most of the PL-4 was acid-labile
Seiji Takeda et al.
Journal of biomedical nanotechnology, 9(2), 303-306 (2013-05-01)
Measurement of oxidized low-density lipoprotein (LDL) generated by oxidative stress of various kinds might be useful for evaluating the risk of cardiovascular disease. We evaluated some electrode materials to detect oxidized LDL electrochemically. Some carbon nanotube dispersions were studied as

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