212806
氯化二乙基铝 溶液
1.0 M in hexanes
别名:
Chlorodiethylaluminum, Dichlorotetraethyldialuminium, Diethylaluminum monochloride
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关于此项目
线性分子式:
(C2H5)2AlCl
化学文摘社编号:
分子量:
120.56
Beilstein:
4123259
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
表单
liquid
质量水平
浓度
1.0 M in hexanes
密度
0.711 g/mL at 25 °C
SMILES字符串
CC[Al](Cl)CC
InChI
1S/2C2H5.Al.ClH/c2*1-2;;/h2*1H2,2H3;;1H/q;;+1;/p-1
InChI key
YNLAOSYQHBDIKW-UHFFFAOYSA-M
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应用
Diethylaluminum chloride solution can be used:
- As a Lewis acid for the synthesis of Lewis acid-base bifunctional asymmetric catalysts for cyanosilylation of aldehydes and in Strecker reaction.
- For the synthesis of precursors for lanthanide/aluminum catalysts for diene polymerization.
- As a co-initiator in the cationic polymerization of isobutylene.
包装
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律信息
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语：
Danger
危险分类
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
靶器官
Central nervous system
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
-7.6 °F
闪点(°C)
-22 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Synthesis of new graft copolymers by combining the DPE technique and cationic polymerization.
Wieland PC, et al.
Macromolecular Rapid Communications, 23(14), 809-813 (2002)
A Catalytic asymmetric Strecker-Type Reaction Promoted by Lewis Acid-Lewis Base Bifunctional Catalvst.
Takamura M, et al.
Chemical & Pharmaceutical Bulletin, 48(10), 1586-1592 (2000)
Lanthanide carboxylate precursors for diene polymerization catalysis: Syntheses, structures, and reactivity with Et2AlCl.
Evans WJ, et al.
Organometallics, 20(26), 5751-5758 (2001)
Highly enantioselective cyanosilylation of aldehydes catalyzed by a Lewis acid-Lewis base bifunctional catalyst.
Hamashima Y, et al
Tetrahedron, 57(5), 805-814 (2001)
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