212849
三甲基氰硅烷
98%
别名:
TMSCN, 氰化三甲基硅烷
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关于此项目
线性分子式:
(CH3)3SiCN
化学文摘社编号:
分子量:
99.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
231-657-3
Beilstein/REAXYS Number:
1737612
MDL number:
产品名称
三甲基氰硅烷, 98%
InChI key
LEIMLDGFXIOXMT-UHFFFAOYSA-N
InChI
1S/C4H9NSi/c1-6(2,3)4-5/h1-3H3
SMILES string
C[Si](C)(C)C#N
assay
98%
form
liquid
refractive index
n20/D 1.392 (lit.)
bp
114-117 °C (lit.)
mp
8-11 °C (lit.)
density
0.793 g/mL at 20 °C (lit.)
Quality Level
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Application
三甲基氰硅烷被用于：
- 通过GC-MS对复杂代谢物混合物进行衍生化
- 作为脂肪族N,N-二烷基腙的对映选择性有机催化Strecker型反应的氰化物源
- 在亚甲硅基桥联稀土氧化物配合物催化的近定量产量醛的氰基甲硅烷基化反应中作为试剂
- 与手性双核Ti（IV）配合物的不对称氰基甲硅烷基化反应
General description
三甲基氰硅烷通过α-甲硅烷氧基腈参与羰基氨甲基化。
Packaging
包装材料含有颗粒状碳酸钠干燥剂。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 2
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
33.8 °F - closed cup
flash_point_c
1 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
非剧毒-急性毒性1
此项目有
Bekzod Khakimov et al.
Analytical and bioanalytical chemistry, 405(28), 9193-9205 (2013-10-05)
Reproducible and quantitative gas chromatography-mass spectrometry (GC-MS)-based metabolomics analysis of complex biological mixtures requires robust and broad-spectrum derivatization. We have evaluated derivatization of complex metabolite mixtures using trimethylsilyl cyanide (TMSCN) and the most commonly used silylation reagent N-methyl-N-(trimethylsilyl)trifluoroacetamide (MSTFA). For
Tetrahedron Asymmetry, 17, 2328-2328 (2006)
Synthetic applications of trimethylsilyl cyanide. Efficient synthesis of. beta.-aminomethyl alcohols.
Evans DA, et al.
The Journal of Organic Chemistry, 39(7), 914-917 (1974)
Aurora Martínez-Muñoz et al.
Organic & biomolecular chemistry, 11(47), 8247-8255 (2013-10-30)
The enantioselective organocatalytic Strecker-type reaction of aliphatic N,N-dialkylhydrazones is presented. Using trimethylsilyl cyanide (TMSCN) as the cyanide source, the reaction can be efficiently catalyzed by a tert-leucine-derived bifunctional thiourea to afford the corresponding hydrazino nitriles in good to excellent yields
Synthetic Communications, 36, 2483-2483 (2006)
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