form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
1.0 M in methylene chloride
density
1.23 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CC(C)C[AlH]CC(C)C
InChI
1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
InChI key
AZWXAPCAJCYGIA-UHFFFAOYSA-N
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General description
二异丁基氢化铝是有机合成中常用的许多官能团的还原剂。
Application
二异丁基氢化铝溶液(1 M 二氯甲烷溶液)已用于在氟碳烷氧基取代的二烷基膦酸阴离子存在条件下通过 Horner-Wadsworth-Emmons 反应酯转化为 α-氟-α,β-不饱和酯。它可用于 ( S )-2-甲基四氢吡啶- N -氧化物的多步合成,是生物活性化合物如希巴辛和螺线菌素-A 的关键结构部分。
用于Pd催化的仲烷基溴的还原脱溴过程。过苄基化呋喃糖苷的O-脱苄基和开环。方便从 ZrCp2Cl2 和DIBAL-H原位生成 HZrCp2Cl。
signalword
Danger
hcodes
target_organs
Central nervous system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 2
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
法规信息
新产品
此项目有
Diisobutylaluminum Hydride.
Galatsis P
e-EROS Encyclopedia of Reagents for Organic Synthesis (2008)
Reduction-olefination of esters: a new and efficient synthesis of. alpha.-fluoro. alpha.,. beta.-unsaturated esters.
Thenappan A
The Journal of Organic Chemistry, 55(15), 4639-4642 (1990)
An enantioselective route to trans-2, 6-disubstituted piperidines
Chackalamannil S
Tetrahedron, 53(32), 11203-11210 (1997)
Reaction of diisobutylaluminum hydride with selected organic compounds containing representative functional groups
Yoon N M
The Journal of Organic Chemistry, 50(14), 2443-2450 (1985)
Takashi Tomioka et al.
The Journal of organic chemistry, 76(11), 4669-4674 (2011-04-30)
Stepwise, selective DIBAL reduction of the acetonide diester derived from tartaric acid followed by the Horner-Emmons reaction effectively provided desymmetrized hydroxy mono-olefination products in a one-pot operation.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 214973-100ML | 04061838773265 |
| 214973-800ML | 04061838773272 |
| 214973-1L | 04061838134981 |
| 214973-PZ | 04061823819749 |
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