grade
technical grade
concentration
65%
refractive index
n20/D 1.488 (lit.)
bp
40 °C/15 mmHg (lit.)
density
0.929 g/mL at 25 °C (lit.)
SMILES string
COC1=CC=CCC1
InChI
1S/C7H10O/c1-8-7-5-3-2-4-6-7/h2-3,5H,4,6H2,1H3
InChI key
LNRUJSUKKBJFOM-UHFFFAOYSA-N
General description
1-Methoxy-1,3-cyclohexadiene is a useful Diels-Alder diene employed in Diels-Alder cycloadditions. It undergoes Diels-Alder reaction with alkyne to yield anisole derivative.
Application
有用的 Diels-Alder 二烯。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
80.6 °F - closed cup
flash_point_c
27 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Bradley O Ashburn et al.
Journal of the American Chemical Society, 129(29), 9109-9116 (2007-07-03)
The application of the Diels-Alder approach to biaryls (DAB) is described for the synthesis of tetra-ortho-substituted biaryl compounds containing orthogonally functionalized substituents. The syntheses of phosphorus-containing, disubstituted alkynes and carbonyl-containing, disubstituted alkynes were accomplished in two to three steps from
Bradley O Ashburn et al.
Organic & biomolecular chemistry, 6(2), 255-257 (2008-01-05)
A series of nitrophenyl acetylenes were evaluated for their utility in a cycloaddition-cycloreversion approach to polysubstituted biaryls. ortho-Nitrophenyl acetylene consistently provided the target biaryls in superior yields as compared to the meta and para nitro substituted variants.
M. Carmen Carreño et al.
The Journal of organic chemistry, 61(18), 6136-6138 (1996-09-06)
The synthesis of tetracyclic polyhydroxyquinones 5a and 5b was achieved through a sequence involving two Diels-Alder reactions with 1-methoxy-1,3-cyclohexadiene: the first with 2-(p-tolylthio)naphthazarin and the second on the resulting tricyclic derivative previously transformed into a (p-tolylsulfinyl)naphthazarin. The success of this
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| W211901-SAMPLE | 04061838100290 |
| W211907-250G-K | 04061838256638 |
| W211907-SAMPLE-K | 04061837502583 |
| W211901-1KG | 04061838256621 |
| 217166-5G | 04061838774750 |