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218235

Sigma-Aldrich

(−)-薄荷酮

90%

别名:

(1R,4S)-对-薄荷烷-3-酮, (2S,5R)-2-异丙基-5-甲基环己酮

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1 G
¥2,267.71

About This Item

经验公式(希尔记法):
C10H18O
CAS Number:
分子量:
154.25
Beilstein:
2041368
EC 号:
MDL编号:
UNSPSC代码:
12352115
PubChem化学物质编号:
NACRES:
NA.22

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蒸汽压

0.5 mmHg ( 20 °C)

质量水平

方案

90%

表单

liquid

旋光性

[α]20/D −20°, neat

杂质

5% isomenthone

折射率

n20/D 1.45 (lit.)

沸点

207-210 °C (lit.)

密度

0.893 g/mL at 20 °C (lit.)

官能团

ketone

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此商品
S5393I4131I4506
biological source

human

biological source

human

biological source

-

biological source

-

conjugate

unconjugated

conjugate

unconjugated

conjugate

unconjugated

conjugate

unconjugated

form

lyophilized powder

form

lyophilized powder

form

essentially salt-free, lyophilized powder

form

essentially salt-free, lyophilized powder

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

packaging

vial of 0.5 mL

packaging

vial of 0.5 mL

packaging

-

packaging

-

contains

15 mM sodium azide

contains

15 mM sodium azide

contains

-

contains

-

一般描述

(-)-薄荷酮是一种单萜化合物,存在于成熟薄荷(Mentha piperita L.)叶提取的精油中。[1]

(-)-薄荷酮经过加氢可生成 (-)-薄荷醇和 (+)-新薄荷醇的混合物。[2]

应用

(-)-薄荷酮可用于合成手性新戊基衍生物[3]、光学纯的 α-二茂铁基烷基胺[4]和光学活性的聚烷基环己酮。[5]

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Skin Irrit. 2 - Skin Sens. 1

储存分类代码

10 - Combustible liquids

WGK

WGK 1

闪点(°F)

165.2 °F

闪点(°C)

74 °C

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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    Oligodeoxynucleotide analogues containing 3'-deoxy-3'-C- threo-hydroxymethylthymidine: Synthesis, hybridization properties and enzymatic stability.
    Svendsen ML, et al.
    Tetrahedron, 49(48), 11341-11352 (1993)
    A Elmblad et al.
    Nucleic acids research, 10(10), 3291-3301 (1982-05-25)
    A method for the synthesis of mixed dimers, trimers and oligonucleotides on a solid support using monomeric protected nucleoside phosphochloridites (1a-d) has been developed and the different nucleoside reagents, and the results show that yields of different oligomers in a
    K Miyoshi et al.
    Nucleic acids research, 8(22), 5473-5489 (1980-11-25)
    Synthesis of two oligothymidylic acids, tridecamer and nonadecamer, is described by a rapid and simple solid-phase method on two kinds of polyacrylamide supports derivatized from commercially available Enzacryl Gel K-2. The syntheses were performed by the phosphotriester method using di-
    Tamara I Prykota et al.
    Nucleosides, nucleotides & nucleic acids, 30(7-8), 544-551 (2011-09-06)
    A new labeling technique attaching a fluorescent pteridine derivative (3, 5) via a linker onto the 3'-OH group of 5'-O-dimethoxytritylthymidine (7) was developed to lead to the conjugates 8 and 11. After detritylation to give 9 and 12, the final
    A Guzaev et al.
    Bioorganic & medicinal chemistry letters, 8(9), 1123-1126 (1999-01-01)
    A novel solid-phase synthesis of 5'-radiolabeled oligonucleotides is described. The labeling reaction is carried out by the phosphoramidite method with the aid of [4,6-di-14C]-5'-dimethoxytritylthymidine building block 1. The feasibility of the method is demonstrated by preparation of 3'-phosphorylated dodecathymidylate phosphorothioate

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