218235
(−)-薄荷酮
90%
别名:
(1R,4S)-对-薄荷烷-3-酮, (2S,5R)-2-异丙基-5-甲基环己酮
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关于此项目
经验公式（希尔记法）:
C10H18O
化学文摘社编号:
分子量:
154.25
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
237-926-1
Beilstein/REAXYS Number:
2041368
MDL number:
产品名称
(−)-薄荷酮, 90%
InChI key
NFLGAXVYCFJBMK-BDAKNGLRSA-N
InChI
1S/C10H18O/c1-7(2)9-5-4-8(3)6-10(9)11/h7-9H,4-6H2,1-3H3/t8-,9+/m1/s1
SMILES string
CC(C)[C@@H]1CC[C@@H](C)CC1=O
vapor pressure
0.5 mmHg ( 20 °C)
assay
90%
form
liquid
optical activity
[α]20/D −20°, neat
impurities
5% isomenthone
refractive index
n20/D 1.45 (lit.)
bp
207-210 °C (lit.)
density
0.893 g/mL at 20 °C (lit.)
functional group
ketone
Quality Level
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Application
（-）-薄荷酮可用于合成手性新戊基衍生物、光学纯的 α-二茂铁基烷基胺和光学活性的聚烷基环己酮。
General description
（-）-薄荷酮是一种单萜化合物，存在于成熟薄荷（Mentha piperita L.）叶提取的精油中。
（-）-薄荷酮经过加氢可生成 (-)-薄荷醇和 (+)-新薄荷醇的混合物。
（-）-薄荷酮经过加氢可生成 (-)-薄荷醇和 (+)-新薄荷醇的混合物。
signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2 - Skin Sens. 1
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
165.2 °F
flash_point_c
74 °C
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of liquid menthol by hydrogenation of dementholized peppermint oil over Ni catalysts
Manuale DL, et al.
Quimica nova, 33, 1231-1234 (2010)
Terpenoids. XLIX. 1 Preparation of Optically Active Polyalkylcyclohexanones from (+)-Pulegone,(-)-Menthone and (-)-Carvone2.
Djerassi C, et al.
Journal of the American Chemical Society, 83(21), 4433-4439 (1961)
Cerium (III) chloride promoted addition of organometallic reagents to (-)-menthone-preparation of chiral neomenthyl derivatives.
Panev S and Dimitrov V.
Tetrahedron Asymmetry, 11(7), 1517-1526 (2000)
Chiral perrocenylalkylamines from (-)-menthone.
Siglmuller F, et al.
Tetrahedron, 42(21), 5931-5940 (1986)
Metabolism of Monoterpenes Demonstration of (+)-Neomenthyl-?-d-Glucoside as a Major Metabolite of (-)-Menthone in Peppermint (Mentha Piperita).
Croteau R and Martinkus C.
Plant Physiology, 64(2), 169-175 (1979)
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