218790
氯化四苯磷
98%, solid
别名:
Chlorotetraphenylphosphorane
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关于此项目
线性分子式:
(C6H5)4P(Cl)
化学文摘社编号:
分子量:
374.84
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
217-890-3
MDL number:
Beilstein/REAXYS Number:
3922393
产品名称
氯化四苯磷, 98%
Quality Level
assay
98%
form
solid
reaction suitability
core: phosphonium
mp
272-274 °C (lit.)
SMILES string
[Cl-].c1ccc(cc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4
InChI
1S/C24H20P.ClH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1
InChI key
WAGFXJQAIZNSEQ-UHFFFAOYSA-M
Application
- 四苯基氯化膦可用于调节 CH 3NH3PbI3 薄膜在沉积过程中的结晶度，以提高钙钛矿型太阳能电池 (PSCs) 器件的性能。
- 与有机金属阴离子络合物反应生成相应的盐。
- 在钯催化的 Heck 反应中也可作为芳基化试剂。
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存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Oxoperoxo molybdenum (vi) and tungsten (vi) and oxodiperoxo molybdate (vi) and tungstate (vi) complexes with 8-quinolinol: synthesis, structure and catalytic activity.
Maiti S K, et al.
New. J. Chem., 29(4), 554-563 (2005)
Tetraarylphosphonium Halides as Arylating Reagents in Pd?Catalyzed Heck and Cross?Coupling Reactions.
Hwang L K, et al.
Angewandte Chemie (International Edition in English), 44(38), 6166-6169 (2005)
Efficient Perovskite Solar Cells with Reduced Photocurrent Hysteresis through Tuned Crystallinity of Hybrid Perovskite Thin Films.
Qi J, et al.
ACS Omega, 3(6), 7069-7076 (2018)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 218790-10G | 04061838775658 |
| 218790-5G | 04061838775672 |
| 218790-50G | 04061838775665 |