218847
三氟化硼二甲醚
别名:
(Dimethyl ether)trifluoroboron
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线性分子式:
BF3 · O(CH3)2
化学文摘社编号:
分子量:
113.87
UNSPSC Code:
12352106
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-532-1
Beilstein/REAXYS Number:
3613739
MDL number:
InChI key
FOWZWMGLMYVYDH-UHFFFAOYSA-N
InChI
1S/C2H6BF3O/c1-7(2)3(4,5)6/h1-2H3
SMILES string
C[O+](C)[B-](F)(F)F
form
liquid
autoignition temp.
455 °F
expl. lim.
21.6 %
reaction suitability
core: boron, reagent type: Lewis acid, reagent type: catalyst
refractive index
n20/D 1.308 (lit.)
bp
126-127 °C (lit.)
mp
−15 °C (lit.)
density
1.239 g/mL at 25 °C (lit.)
functional group
ether
Quality Level
Application
Reactant or reagent involved in:
- Deconvoluting the chemical reaction kinetics of platinum-silver ligand exchange
- Synthesis of neurogenic ganglioside LLG-3 from starfish via glycosylation reactions
- Synthesis of peloruside via lactonization and relay ring-closing metathesis cyclization
- FRET for monitoring Pd-catalyzed nucleophilic allylic substitution reactions
- Single molecuel imaging of fluorophore-tagged palldium(II) complexes
- β-elimination and rearrangement reactions for synthesis of exocyclic vinyl ethers
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 3 - Water-react 1
target_organs
Kidney, Respiratory system
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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