220760
K-Selectride® 溶液
1.0 M potassium tri-sec-butylborohydride in THF
别名:
三仲丁基硼氢化钾 溶液
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选择尺寸
关于此项目
线性分子式:
K[CH(CH3)CH2CH3]3BH
化学文摘社编号:
分子量:
222.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
产品名称
K-Selectride® 溶液, 1.0 M potassium tri-sec-butylborohydride in THF
InChI
1S/C12H28B.K/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
SMILES string
[H][B]([K])(C(C)CC)(C(C)CC)C(C)CC
InChI key
NHEDTYWJTOUTDG-UHFFFAOYSA-N
form
liquid
reaction suitability
reagent type: reductant
concentration
1.0 M potassium tri-sec-butylborohydride in THF
density
0.913 g/mL at 25 °C
Quality Level
Application
- 还原剂
用作以下过程的反应物：
- PCP-钳形钯氢化物-K-选择性配合物的制备
- 氢化物进攻形成 P-H、P-C 和 C-H 键
- 立体选择性共轭氢化物还原反应
酮的立体选择性还原剂。与过渡金属配体发生区域选择性反应的氢化物。
Legal Information
Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F
flash_point_c
-17 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Marlen Putz et al.
Frontiers in chemistry, 8, 435-435 (2020-06-09)
Trenbolone is a synthetic anabolic-androgenic steroid, which has been misused for performance enhancement in sports. The detection of trenbolone doping in routine sports drug testing programs is complex as methods utilizing gas chromatography/mass spectrometry are complicated by unspecific derivatization products
Aldrichimica Acta, 7, 55-55 (1974)
Bulletin of the Chemical Society of Japan, 67, 180-180 (1994)
Journal of Organometallic Chemistry, 462, 353-353 (1993)
J. Chem. Soc., Dalton Trans., 1747-1747 (1993)
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