表单
liquid
浓度
15 wt. % in toluene
密度
0.915 g/mL at 25 °C
SMILES字符串
CC[Zn]CC
InChI
1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;
InChI key
HQWPLXHWEZZGKY-UHFFFAOYSA-N
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应用
与 CF3I 共同用于 Rh(I) 催化的由 α,β-不饱和酮类制备 α-三氟甲基酮类。羰基化合物与二溴氟乙酸酯和三苯基膦经 Wittig 反应合成 α-氟代丙烯酸酯的促进剂。Ni 催化的与环酐的偶联反应。
警示用语：
Danger
危险分类
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1
靶器官
Central nervous system
补充剂危害
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
44.6 °F - closed cup
闪点(°C)
7 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Alkene-directed regioselective nickel-catalyzed cross-coupling of cyclic anhydrides with diorganozinc reagents.
Rebecca L Rogers et al.
Angewandte Chemie (International ed. in English), 46(48), 9301-9304 (2007-11-07)
Synthesis, 3409-3409 (2006)
Organic Syntheses, 83, 177-177 (2006)
Zhiyan Huang et al.
The Journal of organic chemistry, 72(4), 1373-1378 (2007-02-10)
A novel class of sulfinamido alcohol ligands 1-6 was synthesized from (S)-tert-butanesulfinamide. These ligands showed excellent catalytic activities and enantiomeric selectivities in asymmetric additions of diethylzinc to aromatic aldehydes.
Takuji Hirose et al.
The Journal of organic chemistry, 76(13), 5413-5428 (2011-05-20)
Twenty chiral 1,3-amino sulfonamides of two classes (2a-i and 3a-k) have been prepared from (-)-cis-2-benzamidocyclohexanecarboxylic acid (1) and studied as ligands for catalytic enantioselective addition of Et(2)Zn to a variety of aromatic and aliphatic aldehydes. The ligands 2 and 3
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