221171
频哪醇
98%
别名:
2,3-二甲基-2,3-丁二醇, 四甲基乙二醇
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关于此项目
线性分子式:
HOC(CH3)2C(CH3)2OH
化学文摘社编号:
分子量:
118.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-933-5
Beilstein/REAXYS Number:
1340501
MDL number:
产品名称
频哪醇, 98%
InChI key
IVDFJHOHABJVEH-UHFFFAOYSA-N
InChI
1S/C6H14O2/c1-5(2,7)6(3,4)8/h7-8H,1-4H3
SMILES string
CC(C)(O)C(C)(C)O
assay
98%
form
solid
bp
171-172 °C/739 mmHg (lit.)
mp
40-43 °C (lit.)
solubility
alcohol: freely soluble
diethyl ether: freely soluble
hot water: freely soluble
functional group
hydroxyl
Quality Level
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Application
频哪醇是一种1,2-二醇，可用于：
- 作为一种配体，通过与硝酸铀酰和醋酸盐水合物的反应来制备铀酰复合物。
- 使用典型的频哪醇重排反应制备频哪酮和2,3-二甲基-1,3-丁二烯。
- 作为反应剂，合成4-（4,4,5,5-四甲基-1,3,2-二噁硼烷-2-乙基）苯甲酸，用于制备4-乙酸基-3-苯基苯甲醛衍生物。
General description
已有研究报道了以无机电子 [Ca2N](+)·e(−)作为有机溶剂中的电子供体，与角叉菜胶发生频哪醇偶联反应。
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
170.6 °F - closed cup
flash_point_c
77 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synthesis of polymer-bound 4-acetoxy-3-phenylbenzaldehyde derivatives: applications in solid-phase organic synthesis
Kumar A, et al.
The Journal of Organic Chemistry, 71(20), 7915-7918 (2006)
Uranyl complexes with 1, 2-diols and tetrahydrofurfuryl alcohols
Villiers C, et al.
Polyhedron, 46(1), 133-138 (2012)
New extraction procedure for protonated polyoxometalates prepared in aqueous-organic solution and characterisation of their catalytic ability
Ueda T, et al.
Applied Catalysis A: General, 485(1-2), 181-187 (2014)
Fe-substituted molecular sieves as catalysts in liquid phase pinacol rearrangement
Hsien M, et al.
J. Mol. Catal. A: Chem., 181(1-2), 189-200 (2002)
Ye Ji Kim et al.
Chemical communications (Cambridge, England), 50(37), 4791-4794 (2014-04-02)
The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N](+)·e(-) as an electron donor in organic solvents. The bond cleavages of the [Ca2N](+) layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying
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